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When an electric discharge is passed thr...

When an electric discharge is passed through hydrogen gas, the hydrogen molecules dissociate to produce excited to produce excited hydrogen atoms. These excited atoms emit electromagnetic radiation of discrete frequencies which can be given by the general formula
`vecv=109677[(1)/(n_(i)^(2))-(1)/(n_(f)^(2))]`
What points of Bohr's model of an atom can be used to arrive at this formula? Based on these points derive the above formula giving description of each step and each term.

Text Solution

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Two important points of Bohr's model that can be used to derive the given formula are:
(i) Electrons revolve around the nucleus in stationary states, i.e., orbits with fixed values of energy (quantized values).
(ii) Energy is emitted or absorbed only when electron jumps from one orbit to another
Derivation. Step (i) The energy of the electron in the nth stationary state is given by
`E_(n) = - (2pi^(2) me^(4))/(n^(2)h^(2))`
where m = mass of electron, e= charge on electron, h = Planck's constant
Step (ii). When th electron jumps from outer stationay state `n_(2)` to inner stationary state `n_(1)`, the different of energy `(Delta E)` is emitted, i.e.,
`Delta E = E_(2) - E_(1) = - (2pi^(2) me^(4))/(n_(2)^(2) h^(2)) - (-(2pi^(2) me^(4))/(n_(1)^(2) h^(2))) = (2pi^(2) me^(4))/(h^(2)) ((1)/(n_(1)^(2)) - (1)/(n_(2)^(2)))`
Step (iii), `Delta E = hv = h(c)/(lamda) = hc bar(v)`
`:. bar(v) = (Delta E)/(hc) = (2pi^(2) me^(4))/(ch^(3)) ((1)/(n_(1)^(2)) - (1)/(n_(2)^(2)))`
Substituting the value of the constant, `pi, m, e, c and h` in CGS units, we get
`bar(v) = 109677 cm^(-1) ((1)/(n_(1)^(2)) - (1)/(n_(2)^(2)))`
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