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The hydrogen like species Li^(2+) is in ...

The hydrogen like species `Li^(2+)` is in a spherically symmetric state `S_(1)` with one radial node. Upon absorbing light, the ion undergoes transition to a state `S_(2)`. The state `S_(2)` has one radial node and its energy is equal to the ground state energy of the hydrogen atom
The orbital angular momentum quantum number of the state `S_(2)` is

A

0

B

1

C

2

D

3

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The correct Answer is:
To solve the problem regarding the hydrogen-like species \( \text{Li}^{2+} \) and its transition from state \( S_1 \) to state \( S_2 \), we will follow these steps: ### Step 1: Understand the Energy Levels The energy of an electron in a hydrogen-like atom is given by the formula: \[ E_n = -\frac{13.6 \, Z^2}{n^2} \text{ eV} \] where \( Z \) is the atomic number and \( n \) is the principal quantum number. ### Step 2: Determine the Ground State Energy of Hydrogen For hydrogen (\( Z = 1 \)): \[ E_1 = -\frac{13.6 \times 1^2}{1^2} = -13.6 \text{ eV} \] ### Step 3: Set Up the Energy Equation for \( \text{Li}^{2+} \) For \( \text{Li}^{2+} \) (\( Z = 3 \)): \[ E_n = -\frac{13.6 \times 3^2}{n^2} = -\frac{13.6 \times 9}{n^2} = -\frac{122.4}{n^2} \text{ eV} \] ### Step 4: Equate the Energies According to the problem, the energy of state \( S_2 \) is equal to the ground state energy of hydrogen: \[ -\frac{122.4}{n^2} = -13.6 \] ### Step 5: Solve for \( n^2 \) Cancelling the negative signs and rearranging gives: \[ \frac{122.4}{n^2} = 13.6 \] \[ n^2 = \frac{122.4}{13.6} = 9 \] Thus, \( n = 3 \). ### Step 6: Determine the Radial Nodes The number of radial nodes \( R \) is given by the formula: \[ R = n - l - 1 \] We know from the problem that \( R = 1 \) for state \( S_2 \) and \( n = 3 \): \[ 1 = 3 - l - 1 \] Solving for \( l \): \[ 1 = 2 - l \implies l = 1 \] ### Step 7: Identify the Orbital Angular Momentum Quantum Number The orbital angular momentum quantum number \( l \) corresponds to: - \( l = 0 \) for \( s \) orbitals - \( l = 1 \) for \( p \) orbitals - \( l = 2 \) for \( d \) orbitals, etc. Since we found \( l = 1 \), this indicates that the state \( S_2 \) is a \( p \) state. ### Conclusion The orbital angular momentum quantum number of the state \( S_2 \) is: \[ \boxed{1} \]

To solve the problem regarding the hydrogen-like species \( \text{Li}^{2+} \) and its transition from state \( S_1 \) to state \( S_2 \), we will follow these steps: ### Step 1: Understand the Energy Levels The energy of an electron in a hydrogen-like atom is given by the formula: \[ E_n = -\frac{13.6 \, Z^2}{n^2} \text{ eV} \] where \( Z \) is the atomic number and \( n \) is the principal quantum number. ...
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