Home
Class 11
CHEMISTRY
Why are BeSO(4) and MgSO(4) readily solu...

Why are `BeSO_(4)` and `MgSO_(4)` readily soluble in water while `CaSO_(4),SrSO_(4)` and `BaSO_(4)` are insoluble?

Text Solution

Verified by Experts

Because of big size of `SO_(4)^(2-)` ion as compared to `Be^(2+)` and `Mg^(2+)` ions , the lattice enthalpies of `BeSO_(4)` and `MgSO_(4)` are almost the same . But because of small size of `Be^(2+)` and `Mg^(2+)` ions their hydration enthalpies are much higher than their corresponding lattice enthalpies . As a result , `BeSO_(4)` and `MgSO_(4)` are highly soluble in water .
Promotional Banner

Topper's Solved these Questions

  • S-BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS , HINTS AND SOLUTIONS (Matching Type Questions)|3 Videos
  • S-BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS , HINTS AND SOLUTIONS (Assertion and Reason Type Questions)|2 Videos
  • S-BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS , HINTS AND SOLUTIONS (MULTIPLE CHOICE QUESTIONS - II)|7 Videos
  • REDOX REACTIONS

    PRADEEP|Exercise Assertion reason type question|16 Videos
  • SOLID STATE

    PRADEEP|Exercise Advanced problems|19 Videos

Similar Questions

Explore conceptually related problems

BaSO_(4) is insoluble in water due to its

Explain why both BeCO_(3) and BeSO_(4) are unstable to heat, while BaCO_(3) and BaSO_(4) are stable.

Na_(2)SO_(4) is soluble in water whereas BaSO_(4) is sparingly soluble because

Calculate solubility of BasO_(4) when CaSO_(4) and BasO_(4) are dissolved in water simultaneously K_(sp) of CaSO_(4)=p.K_(sp) of BasO_(4)=q and simultaneous solubility of CaSO_(4) is b mol/litre.

The solubility of Na_(2),SO_(4),BeSO_(4),MgSO_(4) and BaSO_(4) will follow the order