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The shape of CH(3)^(-) is..................

The shape of `CH_(3)^(-)` is......................while that of `CH_(3)^(+)` is................. .

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To determine the shapes of the species CH₃⁻ (methyl anion) and CH₃⁺ (methyl cation), we need to analyze their electron pair geometries and steric numbers. ### Step-by-Step Solution: 1. **Identify the Central Atom and Valence Electrons:** - The central atom in both CH₃⁻ and CH₃⁺ is carbon (C). - Carbon has 4 valence electrons. 2. **Analyze CH₃⁻ (Methyl Anion):** - In CH₃⁻, carbon is bonded to three hydrogen atoms and has an extra electron, giving it a total of 5 electrons around it. - The structure can be represented as: - 3 bond pairs (C-H bonds) - 1 lone pair (the extra electron) - **Steric Number Calculation:** - Steric number = Number of bond pairs + Number of lone pairs = 3 (bond pairs) + 1 (lone pair) = 4. - **Electron Geometry:** - With a steric number of 4, the electron geometry is tetrahedral. - **Molecular Shape:** - Since there is one lone pair, the molecular shape is affected. The presence of the lone pair leads to a pyramidal shape (specifically, trigonal pyramidal) due to lone pair-bond pair repulsion being stronger than bond pair-bond pair repulsion. 3. **Analyze CH₃⁺ (Methyl Cation):** - In CH₃⁺, carbon is bonded to three hydrogen atoms but has lost one electron, resulting in a total of 3 electrons around it. - The structure can be represented as: - 3 bond pairs (C-H bonds) - 0 lone pairs. - **Steric Number Calculation:** - Steric number = Number of bond pairs + Number of lone pairs = 3 (bond pairs) + 0 (lone pairs) = 3. - **Electron Geometry:** - With a steric number of 3, the electron geometry is trigonal planar. - **Molecular Shape:** - Since there are no lone pairs, the molecular shape is also trigonal planar. ### Final Answers: - The shape of CH₃⁻ is **pyramidal** (specifically, trigonal pyramidal). - The shape of CH₃⁺ is **trigonal planar**.
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PRADEEP-ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES-Test Your Grip (II. Fill in the Blanks)
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  6. Aldehydes and ketones are ...... ..... isomers.

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  11. The kind of delocalization involving sigma bond orbitals is called:

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  12. Among isomeric butenes, ......... .. is the most stable.

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  14. The shape of CH(3)^(-) is......................while that of CH(3)^(+)...

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