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When n-hexane is heated with anhydrous A...

When n-hexane is heated with anhydrous `AlCl_3` and HCl gas, the major product obtained is

A

1-chlorohexane

B

2-chlorohexane

C

3-chlorohexane

D

mixture of 2-methylpentane and 3-methylpentane

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AI Generated Solution

The correct Answer is:
To solve the question of what major product is obtained when n-hexane is heated with anhydrous AlCl3 and HCl gas, we can follow these steps: ### Step 1: Understand the Reaction When n-hexane (C6H14) is treated with anhydrous AlCl3 and HCl, we are looking at a Friedel-Crafts alkylation reaction. AlCl3 acts as a Lewis acid and helps in generating a more reactive carbocation from the alkane. ### Step 2: Structure of n-Hexane The structure of n-hexane is: ``` CH3-CH2-CH2-CH2-CH2-CH3 ``` This is a straight-chain alkane with six carbon atoms. ### Step 3: Formation of Carbocation When n-hexane is heated with AlCl3 and HCl, a carbocation can be formed. The most stable carbocation that can be formed from n-hexane is the secondary carbocation. ### Step 4: Possible Carbocations The possible carbocations that can be formed from n-hexane are: - 1-hexyl cation (primary, less stable) - 2-hexyl cation (secondary, more stable) - 3-hexyl cation (tertiary, more stable) However, in this case, the secondary carbocation (2-hexyl cation) is the most significant due to its stability. ### Step 5: Alkylation The stable carbocation can then react with the HCl to form an alkyl halide. The alkylation can lead to the formation of branched products. ### Step 6: Identify the Major Products From the reaction, the major products formed will be: - 2-methylpentane - 3-methylpentane ### Conclusion Thus, the major products obtained from the reaction of n-hexane with anhydrous AlCl3 and HCl are a mixture of 2-methylpentane and 3-methylpentane. ### Final Answer The major product obtained is a mixture of 2-methylpentane and 3-methylpentane. ---

To solve the question of what major product is obtained when n-hexane is heated with anhydrous AlCl3 and HCl gas, we can follow these steps: ### Step 1: Understand the Reaction When n-hexane (C6H14) is treated with anhydrous AlCl3 and HCl, we are looking at a Friedel-Crafts alkylation reaction. AlCl3 acts as a Lewis acid and helps in generating a more reactive carbocation from the alkane. ### Step 2: Structure of n-Hexane The structure of n-hexane is: ``` ...
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