Home
Class 12
CHEMISTRY
Which of the following is expected to ge...

Which of the following is expected to generate more stable carbocation on the heterolysis of C-I bond?
`CH_(3)-O-CH_(2)-1, CH_(3)-overset(H)overset(|)(N)-CH_(2)-1`

Text Solution

Verified by Experts

In the first case the carbocation generated is stablized by resonance due to the lone pair of O The same happens in the second case, but now due to the lone pari of . N being less electrogenative can provide electrons easily Hence (ii) is expected to generate more stable carbocation
`CH_(3)-NH-CH_(2)-1rarr[CH_(2)-overset(H)overset(|)(N)-overset(o+)(CH_(2))harrCH_(3)-underset(H)underset(|)overset(o+)(N)=CH_(2)]`
Promotional Banner

Topper's Solved these Questions

  • ORGANIC CHEMISTRY: SOME BASIC PRINCIPLE AND TECHNIQUES

    AAKASH INSTITUTE|Exercise ASSIGNMENT SECTION-A COMPETITION LEVEL QUESTIONS|50 Videos

  • ORGANIC CHEMISTRY: SOME BASIC PRINCIPLE AND TECHNIQUES

    AAKASH INSTITUTE|Exercise SECTION-B OBJECTIVE TYPE QUESTION (ONE OPTION IS CORRECT)|36 Videos

  • ORGANIC CHEMISTRY: SOME BASIC PRINCIPLE AND TECHNIQUES

    AAKASH INSTITUTE|Exercise TRY YOURSELF|28 Videos

  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    AAKASH INSTITUTE|Exercise Assignment(Section-D)(Assertion - Reason Type Questions)|12 Videos

  • POLYMERS

    AAKASH INSTITUTE|Exercise ASSIGNMENT (SECTION-D)|13 Videos

Similar Questions

Explore conceptually related problems

Which of the following is the arranged more stable carbocation of the given species ? CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-overset(o+)CH-CH_(3)to

Which of the following is the rearranged more stable carbocation of the given species? CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C )-overset(o+)(CH)-CH_(3) rarr

CH_(3)-CH_(2)-CH_(2)-O-CH_(3) and CH_(3)-overset(CH_(3))overset(|)(C )H-O-CH_(3) are

Carry out the following transformation in not more than three steps. CH_(3)-CH_(2)-C-=C-H rarr CH_(3)-CH_(2)-CH_(2)-overset(O)overset(||)C-CH_(3)

Write the IUPAC name of the following compound : H_(3)C-overset(Cl)overset(|)(CH)-CH_(2)-overset(O)overset(||)(C)-CH_(3)

CH_(3)CH_(2)CH_(2)-overset(O)overset(||)(C)-H+CH_(3)-C-=CH overset(Na,NH_(3)(l))to

Write IUPAC names of the following compounds : CH_(3)-overset(CH_(3))overset( |)(C)H-CH_(2)-CH_(2)-overset(CH_(3))overset(|)(C)H-CH_(3)

Arrange the following compound is decreasing order of macheophillic addection reation (I) CH_(3)-overset(O)overset(||)(C)-CH_(3) (II) CH_(3)-overset(O)overset(||)(C)-CI (III) CH_(3)-overset(O)overset(||)(C)-NH_(2) (Iv) CH_(3)-overset(O)overset(||)(C)-OH (V) CH_(3)-overset(O)overset(||)(C)-O-overset(O)overset(||)(C)-CH_(3)