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Why the equatiorial and axial bond lengt...

Why the equatiorial and axial bond lengths of `PCl_(5)` are not equl ?

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Sn+PCl_(5) to

All bonds in the molecule of PCl_(5) are not equivalent. Explain.

Statement-1: PCl_(5) exists in ionic solid. Statement-2: PCl_(5) is a covalent compounds. Statement-3: All P-Cl bond lengths in PCl_(5) are equal.

Assertion : In trigonal bipyramidal structure two axial bonds are longer than the equatorial bonds. Reason : Axial bonds suffer more repulsion as compared to equatorial bonds.

Explain the structure of PCl_(5) according to hybridization. Why all P – Cl bonds lengths are not equivalent in PCl_(5) ?

Explain the structure of PCl_(5) according to hybridization. Why all P – Cl bonds lengths are not equivalent in PCl_(5) ?

PRADEEP-CHEMICAL BONDING AND MOLECULAR STRUCTURE-ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS)
  1. Explain the shapes of SF(4) and CIF(3)

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  2. Why PCl(5) dissociates to give PCl(3) and Cl(2)?

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  3. Why the equatiorial and axial bond lengths of PCl(5) are not equl ?

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  4. Which hybridization is presumed for P in PF(3) and S in SF(6) ? Give r...

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  5. What is a coordinate bond ? Explain with two suitable example . How is...

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  6. What is resonance ? Define Resonance energy .

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  7. Draw the resonating structures of CO(2) ?

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  8. Sketch the shapes of molecular orbitals formed by the overlap of (i...

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  9. What do you understand by a molecular orbitals (m.o.) ? What is the ma...

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  10. What is meant by bonding and antibonding molecular orbitals ? Give the...

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  11. What are the condition for combination of atomic orbitals ? Which spec...

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  12. Use the molecular orbital energy level diagram to show that N(2) would...

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  13. What is meant by bond order ? Calculate the bond order of He(2)^(+) ,...

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  14. Calculate the bond order for H(2)^(+) ion. Is this ion expected to be ...

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  15. Arrange the following molecular species in increasing order of satbili...

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  16. Explain why the bond in H(2)^(+) is longer than that in H(2).

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  17. Give the molecular orbitals energy diagram for oxygen molecule and acc...

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  18. Distinguish two aspects of bonding and antibonding orbitals .

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  19. Using MO diagram and occupancy of electrons in orbitals, arrange the f...

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  20. What information does M.O. theory provide for O(2), O(2)^(+), O(2) ^(-...

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