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The strength of the covalent bond in H(2...

The strength of the covalent bond in `H_(2) , F_(2)` and
HF is in the order

A

`H-HgtF-FgtH-F`

B

`H-FgtF-FgtH-H`

C

`H-FgtH-HgtF-F`

D

`F-FgtH-FgtF-F`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the strength of the covalent bonds in H₂, F₂, and HF, we need to analyze the nature of the bonds in each of these molecules. ### Step 1: Identify the Bonds - **H₂ (Hydrogen molecule)**: The bond in H₂ is a single bond formed between two hydrogen atoms (H-H). - **F₂ (Fluorine molecule)**: The bond in F₂ is a single bond formed between two fluorine atoms (F-F). - **HF (Hydrogen fluoride)**: The bond in HF is a polar covalent bond formed between hydrogen and fluorine (H-F). ### Step 2: Analyze Bond Strength - **H-H Bond in H₂**: The H-H bond is relatively strong due to the effective overlap of the 1s orbitals from each hydrogen atom. - **F-F Bond in F₂**: The F-F bond is weaker than the H-H bond. This is primarily due to the presence of three lone pairs of electrons on each fluorine atom, which leads to significant electron-electron repulsion. This repulsion weakens the bond. - **H-F Bond in HF**: The H-F bond is stronger than both the H-H and F-F bonds. This is because the bond involves an sp hybridized orbital from fluorine overlapping with the 1s orbital of hydrogen, which results in a stronger bond compared to the s-s overlap in H₂. ### Step 3: Compare the Strengths Based on the analysis: - The F-F bond is the weakest due to lone pair repulsions. - The H-H bond is stronger than the F-F bond. - The H-F bond is the strongest due to the effective overlap of orbitals. ### Conclusion: Order of Bond Strength Thus, the order of bond strength from weakest to strongest is: **F₂ < H₂ < HF**

To determine the order of the strength of the covalent bonds in H₂, F₂, and HF, we need to analyze the nature of the bonds in each of these molecules. ### Step 1: Identify the Bonds - **H₂ (Hydrogen molecule)**: The bond in H₂ is a single bond formed between two hydrogen atoms (H-H). - **F₂ (Fluorine molecule)**: The bond in F₂ is a single bond formed between two fluorine atoms (F-F). - **HF (Hydrogen fluoride)**: The bond in HF is a polar covalent bond formed between hydrogen and fluorine (H-F). ### Step 2: Analyze Bond Strength ...
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