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The common featrues among the species CN...

The common featrues among the species `CN^(-), CO and CO^(+)` are

A

Bond order three and isoelectronic

B

Bond order three and weak-field ligands

C

Bond order two and `pi-`acceptor

D

Isoelectronic and weak-field ligands

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The correct Answer is:
To determine the common features among the species CN^(-), CO, and CO^(+), we will analyze their electronic configurations, bond orders, and other relevant properties. ### Step-by-Step Solution: **Step 1: Determine the total number of electrons for each species.** - **For CN^(-)**: - Carbon (C) has 6 electrons. - Nitrogen (N) has 7 electrons. - The negative charge (-1) indicates an additional electron. - Total electrons = 6 (C) + 7 (N) + 1 (extra electron) = 14 electrons. - **For CO**: - Carbon (C) has 6 electrons. - Oxygen (O) has 8 electrons. - Total electrons = 6 (C) + 8 (O) = 14 electrons. - **For CO^(+)**: - Carbon (C) has 6 electrons. - Oxygen (O) has 8 electrons. - The positive charge (+1) indicates one less electron. - Total electrons = 6 (C) + 8 (O) - 1 (lost electron) = 13 electrons. **Step 2: Calculate the bond order for each species.** - **Bond Order Formula**: \[ \text{Bond Order} = \frac{\text{Number of bonding electrons} - \text{Number of antibonding electrons}}{2} \] - **For CN^(-)**: - Total electrons = 14. - Bond order = 3.0. - **For CO**: - Total electrons = 14. - Bond order = 3.0. - **For CO^(+)**: - Total electrons = 13. - Bond order = 2.5. **Step 3: Identify common features.** - **Common Electron Count**: - CN^(-) and CO both have 14 electrons, while CO^(+) has 13 electrons. - **Bond Order**: - CN^(-) and CO both have a bond order of 3.0, while CO^(+) has a bond order of 2.5. - **Isoelectronic Species**: - CN^(-) and CO are isoelectronic (same number of electrons), but CO^(+) is not. - **Ligand Field Strength**: - CN^(-) is a weak field ligand, while CO is a strong field ligand. ### Conclusion: The common features among CN^(-), CO, and CO^(+) are: 1. CN^(-) and CO are isoelectronic (both have 14 electrons). 2. CN^(-) and CO have a higher bond order (3.0) compared to CO^(+) (2.5). 3. They all involve carbon and nitrogen/oxygen in their structures.

To determine the common features among the species CN^(-), CO, and CO^(+), we will analyze their electronic configurations, bond orders, and other relevant properties. ### Step-by-Step Solution: **Step 1: Determine the total number of electrons for each species.** - **For CN^(-)**: - Carbon (C) has 6 electrons. ...
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PRADEEP-CHEMICAL BONDING AND MOLECULAR STRUCTURE-COMPETITION FOCUS JEE (Main and Advanced)/ MEDICAL ENTRANCE SPECIAL (I. MULTIPLE CHOICE QUESTIONS WITH ONE CORRECT ANSWER))
  1. Consider the following species CN^(-),CN^(-),NO and CN. Which one ...

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  2. During change of NO^(+)to NO, the electron is added to

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  3. The common featrues among the species CN^(-), CO and CO^(+) are

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  4. Which is the correct statement about sigma and pi molecular orbitals? ...

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  5. Assuming that Hund's rule is violated the bond order and magnetic natu...

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  6. Which statements are correct for the peroxide ion ? (1) It has five ...

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  7. The pairs of species of oxygen and their magnetic behaviour are noted ...

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  8. Which one of the following is not correct with respect to bond length ...

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  9. Which of the following species has lowest ionisation potential?

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  10. Arrange the following ions in the order of decreasing X-O bond length ...

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  11. The correct order in which the O-O bond length increases in the follow...

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  12. In which of the following pairs of molecules/ions, both the species ar...

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  13. According to molecular orbital theory, which of the following will not...

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  14. Stability of the species Li(2), Li(2)^(-) and Li(2)^(+) increases in t...

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  15. Which of the following is paramagnetic?

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  16. Assuming 2s-2p mixing is not operative, the paramagnetic species among...

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  17. The maximum possible number of hydrogen bonds a water molecule can for...

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  18. Which of the following hydrogen halide is most volatile?

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  20. Ortho -nitrophenol is less soluble in water than p-and m-nitrophenols ...

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