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Assuming 2s-2p mixing is not operative, ...

Assuming `2s-2p` mixing is not operative, the paramagnetic species among the following is

A

`Be_(2)`

B

`B_(2)`

C

`C_(2)`

D

`N_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

If `2s - 2p ` mixing is not operative , then molecular
orbitals may be arranged in order of energy as follows :
`sigma (1s), sigma^(**) (1s), sigma(2s), sigma^(**) (2s), sigma(2p_(z)), pi(2p_(x))`
`= (2p_(y)), pi^(**) (2p_(x)) = pi^(**) (2p_(y)), sigma^(**) (2p_(z))`
Applying this configuration , `Be_(2), B_(2) and N_(2)` will
be diamgnetic but `C_(2)` will be paramagnetic .
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