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0.5 mol of H(2), SO(2), and CH(4) is kep...

`0.5 mol` of `H_(2)`, `SO_(2)`, and `CH_(4)` is kept in a container. A hole was made in the container. After `3 hours`, the order of partial pressure in the container will be

A

`p_(SO_(2)) gt p_(CH_(4)) gt p_(H_(2))`

B

`p_(H_(2)) gt p_(SO_(2)) gt p_(CH_(4))`

C

`p_(H_(2)) gt p_(SO_(2)) gt p_(CH_(4))`

D

`p_(H_(2)) gt p_(CH_(4)) gt p_(SO_(2))`

Text Solution

Verified by Experts

The correct Answer is:
A

Equal moles of three gases means equal partial pressures in the beginning. As rate of diffusion
`prop sqrt((1)/("Mol mass"))`, therefore, rates of diffusion will he in the order : `H_(2) gt CH_(4) gt SO_(2)`. Hence, amounts left will be in the order `H_(2) lt CH_(4) lt SO_(2)` or `SO_(2) gt CH_(4) gt H_(2)`. Their partial pressures will also be in the same order.
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