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Unlike phosphorus, nitrogen show little ...

Unlike phosphorus, nitrogen show little tendency for catenation.
Or Phosphorus shows greater tendency for catenation than nitrogen.

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Due to smaller size, the lone pairs of electronc on the two N-atoms repel the bond pair of N-N bond. In contrast, because of comparatively larger size of P, the lone pairs of electrons on the two P atoms do not repel the bond pair of the P-P bond to the same extent. As a result, N-N single bond is weaker `(159kJmol^(-1))` than P-P single bond `(213kJmol^(-1))`. Consequently, nitrogen shows little tendency for catenation or phosphorus has greater tendency for catenation.
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PRADEEP-P-BLOCK ELEMENTS (NITROGEN FAMILY)-CONCEPTUAL QUESTIONS
  1. Give the chemical reaction to support that +5 oxidation state of Bi is...

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  2. Bismuth is a strong oxidizing agent in the pentavalent state. Or penta...

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  3. Why is Bi(V) a stronger oxidant than Sb(V) ?

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  4. Explain why both N and Bi do not form pentahalides while phosphorus do...

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  5. NH(3) has higher proton affinity than PH(3). Explain. Or NH(3) is more...

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  6. You have the following substances :NH(3),O(2),andH(2)O. Write equation...

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  7. Although nitrogen and chlorine have very nearly same electronegativity...

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  8. Although fluorine is much more electronegative than hydrogen yet the d...

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  9. Unlike phosphorus, nitrogen show little tendency for catenation. Or ...

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  10. Ammonia is a good complexing agent. Give reasons. Or Ammonia acts as...

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  11. Why is N(2)O(5) more acidic than N(2)O(3) ?

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  12. Give reasons for the following : (i) NO (Nitric oxide) is paramagnet...

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  13. In the structure of HNO(3), why is N-O bond (121 pm) shorter than N-OH...

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  14. Why is nitrous acid oxidant as well as reductant?

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  15. Draw the structure of white phosphorus and red phosphorus. Which one o...

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  16. PCl(5) is ionic in nature in the solid state. Give reasons. Or Solid...

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  17. Draw the structure of PCl(5). Or Solid PCl(5) is ionic in nature.

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  18. Given chemical reaction in support of the statement that all the bonds...

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  19. H(3)PO(3) is diprotic (or dibasic). Why ? Or What is the basicity of...

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  20. H(3)PO(3) undergoes disproportionation reaction but H(3)PO(4) does not...

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