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[Fe(H(2)O)(5)NO]^(2+) is a complex forme...

`[Fe(H_(2)O)_(5)NO]^(2+)` is a complex formed during the brown ring test for `NO_(3)^(-)` ion. In this complex.

A

there are there unpaired electrons so that its magnetic moment is 3.87 B.M.

B

NO transfers its electron to `Fe^(2+)` so that iron exists as Fe (I) and NO as `NO^(+)`

C

the colour is because of charge transfer

D

all of the above statements are correct

Text Solution

Verified by Experts

The correct Answer is:
D

`:overset(*)N=underset(* *)O:to:overset(+)N=underset(* *)O:+e^(-)`
`Fe^(2+)e^(-)toFe^(+)`

`:.` Magnetic moment of `Fe^(+)=sqrt(n(n+2))BM`
`=sqrt(3xx5)BM=3.87BM`
All statements are correct.
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