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What will be the resultant products form...

What will be the resultant products formed when the phosphorus hailde `PBr_(5)` splits up ?

A

`[PBr_(4)]^(+)andBr^(-)`

B

`[PBr_(6)]^(-)and[PBr_(4)]^(+)`

C

`[PBr_(4)]^(+)`

D

`[PBr_(6)]^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the resultant products formed when phosphorus pentabromide (PBr₅) splits up, we need to analyze its structure and stability. ### Step-by-Step Solution: 1. **Understanding the Structure of PBr₅**: - PBr₅ has a trigonal bipyramidal (TBP) geometry. This means it has five bromine atoms surrounding a central phosphorus atom, with three bromine atoms in a plane (equatorial positions) and two bromine atoms above and below this plane (axial positions). **Hint**: Recall the geometry of PBr₅ and how it affects its stability. 2. **Stability of PBr₅**: - PBr₅ is not very stable due to its geometry. The presence of large bromine atoms creates steric strain, making it more favorable for the molecule to break apart into more stable forms. **Hint**: Consider why certain molecular geometries lead to instability. 3. **Dissociation of PBr₅**: - When PBr₅ dissociates, it tends to lose one bromine atom. This results in the formation of phosphorus tetrabromide (PBr₄) and a bromide ion (Br⁻). **Hint**: Think about how the loss of a bromine atom affects the phosphorus compound. 4. **Resultant Products**: - The products formed from the dissociation of PBr₅ are: - PBr₄ (phosphorus tetrabromide) - Br⁻ (bromide ion) **Hint**: Identify the products based on the number of bromine atoms remaining and their charges. ### Final Answer: When phosphorus pentabromide (PBr₅) splits up, it forms phosphorus tetrabromide (PBr₄) and a bromide ion (Br⁻). ### Summary of Steps: 1. Identify the structure of PBr₅. 2. Assess its stability based on geometry. 3. Determine the dissociation process. 4. List the resultant products.

To determine the resultant products formed when phosphorus pentabromide (PBr₅) splits up, we need to analyze its structure and stability. ### Step-by-Step Solution: 1. **Understanding the Structure of PBr₅**: - PBr₅ has a trigonal bipyramidal (TBP) geometry. This means it has five bromine atoms surrounding a central phosphorus atom, with three bromine atoms in a plane (equatorial positions) and two bromine atoms above and below this plane (axial positions). **Hint**: Recall the geometry of PBr₅ and how it affects its stability. ...
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PRADEEP-P-BLOCK ELEMENTS (NITROGEN FAMILY)-Competition focus jee(main and advanced)/ medical entrance special) (I. Multiple Choice Questions (with one correct answer)
  1. Maximum number of covalent bonds formed by N and P are

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  2. The percentage of p-character in the orbitals forming p-p bonds in P4 ...

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  3. Which one of the following forms vortex ring

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  4. The reaction of white phosphorus with aqueous NaOH gives phosphine alo...

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  5. The reaction of P(4) with X leads selectively to P(4)O(6) The X is :

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  6. P(4)O(10) is the anhydride of

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  7. How many bridging atoms are present in P(4)O(10) ?

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  8. Of the following compounds, the most acidic is

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  9. Oxidation state of phosphorus in cyclotrimetaphosphoric acid is

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  10. The correct formula of salt formed by the neutraliation of hypophosph...

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  11. The oxoacid of phosphorus that reduces silver nitrate into metallic si...

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  12. The pair in which phosphours atoms have a formed oxidation state of +3...

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  13. Which is the correct statement for the given acids ?

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  14. Which of the following is a cyclic oxo acid ?

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  15. Sulphuryl chloride (SO(2)Cl(2)) reacts with white phosphorus (P(4)) to...

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  16. Cl-P-Cl bond angles in PCl5 molecule are

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  17. The compound which has molecular nature in gas phase but ionic in soli...

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  18. What will be the resultant products formed when the phosphorus hailde ...

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  19. Excess of PCl(5) reacts with concentrated H(2)SO(4) giving :

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  20. Reaction of PCl3 and PhMgBr would give

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