Home
Class 12
CHEMISTRY
The EMF of the following cell is found t...

The EMF of the following cell is found to be 0.20 V at 298 K
`Cd|Cd^(2+)(?)||Ni^(2+)(2.0M)|Ni`
What is the molar concentration of `Cd^(2+)` ions in the solution?
`(E_(Cd^(2+)//Cd)^(@)=-0.40V,E_(Ni^(2+)//Ni)^(@)=-0.25V)`

Text Solution

AI Generated Solution

To find the molar concentration of \( \text{Cd}^{2+} \) ions in the solution, we can use the Nernst equation, which relates the cell potential (EMF) to the concentrations of the reactants and products. ### Step-by-Step Solution: 1. **Identify the Cell Reaction:** The cell reaction can be represented as: \[ \text{Cd}^{2+} + 2 \text{e}^- \rightarrow \text{Cd} \quad (E^\circ = -0.40 \, \text{V}) ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    PRADEEP|Exercise Sample Problem|15 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise Curiosity Question|5 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos

Similar Questions

Explore conceptually related problems

Al|Al_(0.5 M)^(+3)|| Cd_(0.02M)^(+2)| What will be the electromotive force of this cell at 25^(@)C E_(Cd^(+2)//Cd)^(@) =-0.40 V, E_(Al//Al^(+3))^(@) =+1.66 V

Calculate the equilibrium constant for the reaction : Fe(s)Cd^(2+)(aq)harrFe^(2+)(aq)+Cd(s) ("Given" E_(cd^(2+)//Cd)^(@)=-0.40 V, E_(Fe^(2+)//Fe)^(@)=-0.44 V)

Calculate e.m.f. of the cell containing nickel and copper electrodes. Given that : E_(Ni^(2+)//Ni)^(@)=-0.25 V , E_(Cu^(2+)//Cu)^(@)=+0.34 V.

Calculate the emf for the following cell at 298 K. Cd//Cd^(2+)(0.1 M) || Ag^(+)(0.1 M)//Ag "Given"E_(Cd^(2+)//Cd)^(@)=-0.40" V ",E_(Ag^(+)//Ag)^(@)=0.80" V "

If the equilibrium constant for the reaction Cd^(2+)(aq)+4NH_3(aq)iffCd(NH_3)_4^(2+)(aq) is 10^x then find the value of x. (Given: E_(Cd^(2+)"|"Cd)^(@)=-0.4V,E_(Cd(NH_3)_4^(2+)"|"Cd)^(@)=-0.61V )

PRADEEP-ELECTROCHEMISTRY-IMPORTANT QUESTIONS FOR BOARD EXAMINATION
  1. The EMF of the following cell is found to be 0.20 V at 298 K Cd|Cd^(...

    Text Solution

    |

  2. A current is passed through two cells connected in series. The first c...

    Text Solution

    |

  3. Predict the products of electrolysis in eaCHM of the following : a. ...

    Text Solution

    |

  4. On passing electric current of one ampere for 16 min and 5 sec through...

    Text Solution

    |

  5. The elctrical resistance of a column of 0.05 M N aOH solution of diam...

    Text Solution

    |

  6. Resistance of a conductivity cell filled with 0.1 mol L^(-1) KCl solut...

    Text Solution

    |

  7. Which out of 0.1 M HCl and 0.1 M NaCl, do you expect to have greater L...

    Text Solution

    |

  8. Why does the conductivity of a solution decrease with dilution ?

    Text Solution

    |

  9. (a) What do you mean by Electrolytic cell? (b) An electrochemical ce...

    Text Solution

    |

  10. What is the effect of increase in concentration of CuSO(4) solution on...

    Text Solution

    |

  11. Why is it not possible to measure the single electrode potential ?

    Text Solution

    |

  12. What do you understand by normal hydrogen electrode? Give its construc...

    Text Solution

    |

  13. What does the negative sign in the expression E(Zn^(2+)//Zn)^(@)=-0.76...

    Text Solution

    |

  14. The emf (E^(@)) of the following cels are : Ag|Ag^(+) (1 M)||Cu^(2+)...

    Text Solution

    |

  15. Is it safe to stir 1M AgNO(3) solution with copper spoon? Given:E^(@)A...

    Text Solution

    |

  16. I(2) and F(2) are added toa asolution containing 1M each of I^(-) an...

    Text Solution

    |

  17. On the basis of the standard electroe potential values stated for acid...

    Text Solution

    |

  18. Two half cell reactions of an electrochemical cell are given below : ...

    Text Solution

    |

  19. Given standard electrode potentials K^(o+)|K=-2.93V, Ag^(o+)|Ag=0.80...

    Text Solution

    |

  20. When acidulated water (dil. H(2)SO(4) solution) is electrolysed, with ...

    Text Solution

    |

  21. Calculate the potential for half cell containing 0.10 M K(2)Cr(2)O(7)(...

    Text Solution

    |