Home
Class 12
CHEMISTRY
Write the CHMemistry of reCHMarging of l...

Write the CHMemistry of reCHMarging of lead storage battery highlighting all the materials that are involved during reCHMarging.

Text Solution

Verified by Experts

A lead storage battery consists of anode of lead, cathode of a grid of lead packed with lead dioxide `(PbO_(2))` and 38% solution of sulphuric acid as electrolytic. When the battery is in use, the following reactions take place: ltBrgt At anode: `Pb(s)+SO_(4)^(2-)(aq)toPbSO_(4)(s)+2e^(-)` . . . (i)
At cathode: `PbO_(2)(s)+SO_(4)^(2-)(aq)+4H^(+)(aq)+2e^(-)toPbSO_(4)(s)+2H_(2)O(l)` . . . (ii)
Overall reaction: `overline(Pb(s)+PbO_(2)(s)+2H_(2)SO_(4)(aq)to2PbSO_(4)(s)+2H_(2)O(l)" ")`
On charging the battery, the reverse reactio takes place, i.e., `PbSO_(4)` deposited on the electrodes is oververted back into Pb and `PbO_(2)` and `H_(2)SO_(4)` is regenerated. Reverse of reaction (i) will be reduction and hence will take place at cathode. reverse of reaction (ii) will be oxidation and hence will take place at anode.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    PRADEEP|Exercise NCERT EXERCISES|16 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MULTIPLE QUESTIONS-I)|39 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise CONCEPTUAL QUESTIONS|46 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos

Similar Questions

Explore conceptually related problems

As lead storage battery is charged

During discharging of alead storage battery

Lead storage battery contains

While charging the lead storage battery:

Write the overall cell reaction for lead storage battery.