Home
Class 12
CHEMISTRY
For pure water degree of dissociation ...

For pure water degree of dissociation of water is `1.9xx10^(-9)`
`wedge_(m)^(infty)(H^(+))=350 Scm^(2) mol^(-1)`
`wedge_(m)^(infty)(OH^(-))=200 S cm^(2) mol^(-1)`
Hence molar conductance of water is

A

`3.8xx10^(-7)" S "cm^(2)mol^(-1)`

B

`5.7xx10^(-7)" S "cm^(2)mol^(-1)`

C

`9.5xx10^(-7)" S "cm^(2)mol^(-1)`

D

`1.045xx10^(-6)" S "cm^(2)mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
D

Degree of dissociation `(alpha)=(wedge_(m)^(c))/(wedge_(m)^(0))`
`wedge_(m)^(c)=alphaxxwedge_(m)^(0)=(1.9xx10^(-9))xx(200+350)" S "cm^(2)mol^(-1)`
`=1.9xx550xx10^(-9)=1.045xx10^(-6)" S "cm^(2)mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    PRADEEP|Exercise VALUE BASED QUESTIONS WITH ANWER (Multiple Choice Questions-II)|7 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise VALUE BASED QUESTIONS WITH ANWER (Multiple Choice Questions-III Based on the given Passage/Comprehension)|13 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise HIGHER ORDER THINKING SKILLS (HOTS PROBLEMS)|13 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos

Similar Questions

Explore conceptually related problems

Calcualte acid dissociatioin constant for 0.1 M HCOOH if its solution shows a resistance of 50 Omega filled in a cell having separation beween parallel electrodes 4 cm and cross section area of electrode 10 cm^(2) . [Given: Lambda_(m)^(infty)[Ca(HCCO)_(2)] = 230 Scm^(2)mol^(-) lambda_(m)^(infty)[CaCl_(2)] = 280 Scm^(2) mol^(-1) lambda_(m)^(infty) [HCl] = 425 Scm^(2) mol^(-1) ] In scientific notation, x xx 10^(-y) , find the value of y.

The conductivity of 0.001 "mol" L^(-1) solution of CH_(3)COOH " is " 3.905 xx 10^(-5) "S" cm^(-1) . Calculate its molar conductivity and degree of dissociation (alpha) . "Given" lambda^(@) (H^(+)) = 349.6 "S" cm^(2) "mol"^(-1) " and " lambda^(0) (CH_(3)COO^(-)) = 40.9 "S" cm^(2) "mol"^(-1) (b) Define electrochemical cell. What happens if external potential applied becomes greater than E_(cell)^(@) of electrochemical cell?

Molar conductivity of aqueous solution of HA is 200 S cm^(2) "mol"^(-1) , pH of this solution is 4. Calculate the value of pK_(a) (HA) at 25^(@) C Given: wedge_(M)^(infty) (NaA) = 100 S cm^(2) mol^(-1), wedge_(M)^(infty)(HCl)= 425 Scm^(2) "mol"^(-1) , wedge_(M)^(infty)(NaCl) = 125 Scm^(2)"mol"^(-1) .

PRADEEP-ELECTROCHEMISTRY-VALUE BASED QUESTIONS WITH ANWER (Multiple Choice Questions-I)
  1. Ionic mobility of which of the following alkali metal ions is lowest w...

    Text Solution

    |

  2. Ionic mobility of Ag^(+) is (lamda(Ag^(+))=5xx10^(-4)ohm^(-1)cm^(2)eq^...

    Text Solution

    |

  3. For pure water degree of dissociation of water is 1.9xx10^(-9) we...

    Text Solution

    |

  4. Equivalent condictance of BaCI(2), H(2)SO(4) and HCI are x(1) , x(2) a...

    Text Solution

    |

  5. Equivalent conductivity at infinite dilution for sodium potassium oxal...

    Text Solution

    |

  6. The reaction taking place in the cell Pg|H(2)(g)|HCl(1.0M)|AgCl|Ag is ...

    Text Solution

    |

  7. When measured against a standard calomel electrode, an electrode is fo...

    Text Solution

    |

  8. Which has maximum potential for the half-cell reaction : 2H^(+)2e^(-) ...

    Text Solution

    |

  9. Quinhydrone electrode is sometimes used to find the pH of a solution. ...

    Text Solution

    |

  10. Given E(Cr^(3+)//Cr^(@))= -O*74V,E(MnO(4)^(-)//Mn^(2+))^(@) = 1.51V E...

    Text Solution

    |

  11. Given E(Cl(2)//Cl^(-))^(@)=1.36V,E(Cr^(3+)//Cr)^(@)=-0.74V E("Cr(2)O...

    Text Solution

    |

  12. Standard reduction potentials of the half reactions are given below ...

    Text Solution

    |

  13. Small quantities of compounds TX, TY and TZ are put into separate test...

    Text Solution

    |

  14. Which of the following statements are correct concerning redox propert...

    Text Solution

    |

  15. The standard reduction potentials for Zn^(2+)//Zn,Ni^(2+)//Niand Fe^(2...

    Text Solution

    |

  16. Standard electrode potential for Sn^(4+)//Sn^(2+) couple is +0.15 V an...

    Text Solution

    |

  17. A button cell used in watched funcations as follwing Zn(s)+Ag(2)O(s)...

    Text Solution

    |

  18. A solution contains Fe^(2+), Fe^(3+) and T^(-) ions. This solution was...

    Text Solution

    |

  19. Given that E(Fe^(2+)//Fe)^(.)=-0.44V,E(Fe^(3+)//Fe^(2+))^(@)=0.77V if...

    Text Solution

    |

  20. Zn gives H(2) gas with H(2)SO(4) and HCl but not with HNO(3) because

    Text Solution

    |