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Given E(Cl(2)//Cl^(-))^(@)=1.36V,E(Cr^(3...

Given `E_(Cl_(2)//Cl^(-))^(@)=1.36V,E_(Cr^(3+)//Cr)^(@)=-0.74V`
`E_("Cr_(2)O_(7)^(2-)//Cr^(3+))^(@)=1.33V,E_(MnO_(4)^(-)//Mn^(2+))^(@)=1.51V`
Among the following, the strongest reducing agent is

A

`Cr^(3+)`

B

`Cl^(-)`

C

`Cr`

D

`Mn^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
C

Greater the standard oxidation potential (or lesser is the standard reduction potential), more easily the substance is oxidized and hence stronger is the reducing is oxidized and hence stronger is the reducing agent. As `E_(Cr^(+3)//Cr)^(@)` (i.e., standard reduction potential) is lowest, hence, Cr will be strongest reducing agent.
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Given E_("Cr_(2)O_(7)^(2-)//Cr^(3+))^(@)=1.33V,E_(MnO_(4)^(-)//Mn^(2+))^(@)=1.51V Among the following, the strongest reducing agent is E_(Cr^(3+)//Cr)^(@)=-0.74V^(x),E_(MnO_(4)^(-)//Mn^(2+))^(@)=1.51V E_(Cr_(2)O_(7)^(2-)//Cr^(3+))^(@)=1.33V,E_(Cl//Cl^(-))^(@)=1.36V Based on the data given above strongest oxidising agent will be

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