Home
Class 12
CHEMISTRY
Standard reduction potentials of the hal...

Standard reduction potentials of the half reactions are given below
`{:(F_(2(g))+2e^(-) rarr 2F^(-)""_((aq)),,E^(@)=+2.85V), (Cl_(2(g))+2e^(-) rarr 2Cl^(-)""_((aq)),, E^(@)=+1.36V), (Br_(2(l))+2e^(-) rarr 2Br^(-)""_((aq)),,E^(@)=+1.06V), (l_(2(s))+2e^(-) rarr 2l^(-)""_((aq)),, E^(@)=+0.53V):}`
The strongest oxidising and reducing agents respectively are

A

`Cl_(2) and Br^(-)`

B

`Cl_(2) and I_(2)`

C

`F_(2) and I^(-)`

D

`Br_(2) and Cl^(-)`

Text Solution

Verified by Experts

The correct Answer is:
C

Higher the reduction potential, more easily it is reduced and hence stronger is the oxidizing agent. `F_(2)` has highest reduction potential. Hence, `F_(2)` is strongest oxidizing agent. Considering the reverse reaction (oxidation reaction), higher the oxidation potential, more easily it is oxidized and hence stronger is the reducing agent. oxidation potential of `I^(-)` ion `(-0.53V)` is highest out of -2.85,-1.36,,-1.06 and -0.53. hence, `I^(-)` is strongest reducing agent.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    PRADEEP|Exercise VALUE BASED QUESTIONS WITH ANWER (Multiple Choice Questions-II)|7 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise VALUE BASED QUESTIONS WITH ANWER (Multiple Choice Questions-III Based on the given Passage/Comprehension)|13 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise HIGHER ORDER THINKING SKILLS (HOTS PROBLEMS)|13 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos

Similar Questions

Explore conceptually related problems

Standard reduction potentails of the half reactions are given below: F_(2)(g)+2e^(-) rarr 2F^(-)(aq.),, E^(ɵ)= +2.87 Cl_(2)(g)+2e^(-) rarr 2Cl^(-)(aq.),, E^(ɵ)= +1.36 V Br_(2)(g)+2e^(-) rarr 2Br^(-)(aq.),, E^(ɵ)= +1.09 V I_(2)(s)+2e^(-) rarr 2l^(-)(aq.),, E^(ɵ)= +0.54 V The strongest oxidizing and reducing agents respectively are:

Standrd reduction potentials of the half reactions are given below : F_2 (g) +re^- rarr 2 F^(-) (aq) E^@ = + 2.85 V Cl_2 (g) +2e^- rarr 2 Cl^-(aq) , E^2 = + 1.36 V Br _2 (i) + 2 e^- rarr 2Br (aq) , E^2 = + 1. 06 V I_2 (s) + 2 e^- rarr 2I^(-) (aq) , E^2 = + . 53 V . The strongest oxidizing and reducing agents respectively

PRADEEP-ELECTROCHEMISTRY-VALUE BASED QUESTIONS WITH ANWER (Multiple Choice Questions-I)
  1. Given E(Cr^(3+)//Cr^(@))= -O*74V,E(MnO(4)^(-)//Mn^(2+))^(@) = 1.51V E...

    Text Solution

    |

  2. Given E(Cl(2)//Cl^(-))^(@)=1.36V,E(Cr^(3+)//Cr)^(@)=-0.74V E("Cr(2)O...

    Text Solution

    |

  3. Standard reduction potentials of the half reactions are given below ...

    Text Solution

    |

  4. Small quantities of compounds TX, TY and TZ are put into separate test...

    Text Solution

    |

  5. Which of the following statements are correct concerning redox propert...

    Text Solution

    |

  6. The standard reduction potentials for Zn^(2+)//Zn,Ni^(2+)//Niand Fe^(2...

    Text Solution

    |

  7. Standard electrode potential for Sn^(4+)//Sn^(2+) couple is +0.15 V an...

    Text Solution

    |

  8. A button cell used in watched funcations as follwing Zn(s)+Ag(2)O(s)...

    Text Solution

    |

  9. A solution contains Fe^(2+), Fe^(3+) and T^(-) ions. This solution was...

    Text Solution

    |

  10. Given that E(Fe^(2+)//Fe)^(.)=-0.44V,E(Fe^(3+)//Fe^(2+))^(@)=0.77V if...

    Text Solution

    |

  11. Zn gives H(2) gas with H(2)SO(4) and HCl but not with HNO(3) because

    Text Solution

    |

  12. Cr(2)O(7)^(2-)+I^(-)toI(2)+Cr^(3+) E(cell)^(@)=0.79V,E(Cr(2)O(7)^(2-...

    Text Solution

    |

  13. Aluminium displaces hydrogen from dilute HCl whereas silver does not. ...

    Text Solution

    |

  14. An aqueous solution containing one mole per litre of each Cu(NO(3))(2...

    Text Solution

    |

  15. The EMF of a cell formed by combining a particular electrode with stan...

    Text Solution

    |

  16. Given below are the half -cell reactions Mn^(2+)+2e^(-) to Mn, E^(@)...

    Text Solution

    |

  17. A hydrogen gas electrode is made by dipping platinum wire in a solutio...

    Text Solution

    |

  18. How much will the reduction potential of a hydrogen electrode change w...

    Text Solution

    |

  19. Calculate the reduction potential of a half cell consisting of a plati...

    Text Solution

    |

  20. The reduction potential of hydrogen half cell will be negative if :

    Text Solution

    |