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A hydrogen gas electrode is made by dipp...

A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl or `pH = 10` and by passing bydrogen gas around the platinum wire at one atm pressure . The oxidation potential of electrode would be ?

A

0.059 V

B

0.59 V

C

0.118 V

D

0.18 V

Text Solution

Verified by Experts

The correct Answer is:
C

For hydrogen electrode, reduction reaction is
`H^(+)+e^(-)to(1)/(2)H_(2)`
`E_(H^(+)//(1)/(2)H_(2))^(@)=E_(H^(+)//(1)/(2)H_(2))^(@)-(0.0591)/(n)"log"(p_(H_(2))^(1//2))/([H^(+)])`
`=0-(0.0591)/(n)"log"(1)/(10^(-10))=-0.591`
`(pH=10" means "[H^(+)]=10^(-10)M)`
`therefore`Oxidation potential`=0.591V`
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