Home
Class 12
CHEMISTRY
The E^(@) value in respect of the electr...

The `E^(@)` value in respect of the electrodes `(Z=24)`, manganese `(Z=25)` and iron `(Z=26)` are :

`Cr^(3+)//Cr^(2+)=-0.4V,Mn^(3+)//Mn^(2+)=+1.5V`,`Fe^(3+)//Fe^(2)=+0.8V`.

On the basic of the above information compare the feasibilities of further oxidation of their `+2` oxidation states.

Text Solution

Verified by Experts

`-ve` value of `E^(@)` for `Cr^(3+) //Cr^(2+)` shows that `Cr^(2+)` is least stable. Greater `+ve` value for `Mn^(3+)// Mn^(2+)` than that for `Fe^(3+) //Fe^(2+)` shows that `Mn^(2+)` is more stable than `Fe^(2+)` . Hence, stability of `+2` oxidation state is in the order `: Cr^(2+) lt Fe^(2+) lt Mn^(2+)` or the oxidation of their `+2` state to `+3` state is in the order `: Cr^(2+) gt Fe^(2+) gt Mn^(2+)`
Promotional Banner

Topper's Solved these Questions

  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise NCERT (QUESTIONS AND EXERCISES WITH ANSERS)|10 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise NCERT INTEXT UNSOLVED QUESTIONS|10 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise TEST YOUR GRIP( FILL IN THE BLANKS)|33 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Important Questions|28 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|25 Videos

Similar Questions

Explore conceptually related problems

For Mn^(3+)//Mn^(2+) system, the E^(0) values for some metals are as follows: Cr^(3+)//Cr^(2+)(-0.4V) , Mn^(3+)//Mn^(2+) (+1.5V) , Fe^(3+)//Fe^(2+)(+0.8V) . Then the relative stabilities of Fe^(3+), Cr^(3+) and Mn^(3+) is :

For M^(2+)//M and M^(3+)//M^(2+) system, the E^(@) value of some metals are given : Cr^(2+)//Cr=0.9V,Cr^(3+)//Cr^(2+)=-0.4V Mn^(2+)//Mn=1.2V,Mn^(3+)//Mn^(2+)= +1.5 V Fe^(2+)//Fe=0.4 V, Fe^(3+)//Fe^(2+)= +0.8 V Use this data to comment upon : (a) The stability of Fe^(3+) in acid solution as compared to that of Cr^(3+) or Mn^(3+) (b) The ease with which iron can be oxidised as compared to the similar process for either chromium or manganese metal.

Magnetic moment of Cr(Z=24), Mn^+(Z=25) and Fe^(2+)(Z=26) are x,y,z. They are in order

Magnetic moment of Cr^(+2)(Z=24),Mn^(+2)(Z=25) and Fe^(2+) (Z=26) are x,y,z. they are in order

PRADEEP-D- AND F-BLOCK ELEMENTS-CONCEPTUAL QUESTIONS
  1. Most of the transition metals do not displace hydrogen from dilute aci...

    Text Solution

    |

  2. Explain why E^(@) for Mn^(3+)//Mn^(2+) couple is more positive than th...

    Text Solution

    |

  3. The E^(@) value in respect of the electrodes (Z=24), manganese (Z=25) ...

    Text Solution

    |

  4. Why do transition elements show variable oxidation state?

    Text Solution

    |

  5. How is the variability in oxidation states fo transition metals differ...

    Text Solution

    |

  6. Among lanthanoids, Ln (III) compounds are predominant. However, occasi...

    Text Solution

    |

  7. How would you account for the fact that the transition metals and thei...

    Text Solution

    |

  8. Why generally there is an increase in density of elements from titani...

    Text Solution

    |

  9. Giving reasons indicate which one of the following would be coloured ?...

    Text Solution

    |

  10. Scandium forms no coloured ions, yet it is regarded as a transition el...

    Text Solution

    |

  11. A substance is found to have a magnetic moments of 3.9BM.How many unpa...

    Text Solution

    |

  12. The paramagnetic character in 3d transition series elements increases ...

    Text Solution

    |

  13. Decide giving reason which one of the following pairs exhibits the pr...

    Text Solution

    |

  14. (a) of the ions Ag^(+),Co^(2+) and Ti^(+), which one will be coloured ...

    Text Solution

    |

  15. Why are the ionisation energies of 5d elements greater than 3d element...

    Text Solution

    |

  16. Describe giving reason which one of the following pairs has the proper...

    Text Solution

    |

  17. Give reason for the following features of transition metal chemistry: ...

    Text Solution

    |

  18. The 4d and 5d series of transition metals have more frequency metal-me...

    Text Solution

    |

  19. Give reasons for each of the following: (i) Size of trivalent lantha...

    Text Solution

    |

  20. Assign reason for each of the following statement: (i) The largest n...

    Text Solution

    |