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How would you account for the fact that ...

How would you account for the fact that the transition metals and their compounds are found to be good catalysts in many processes?

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According to activated complex theory ( intermediate compound formation theory ), due to variable oxidation states, transition metal combines with the reactant `//`s to forma an intermediate ( an unstable species ) called activated complex whichi finally decomposes to form the products regenerating the catalyst.
`underset("Reactant")(A) + underset("catalyst")(C) rarr underset("(Intermediate)")underset("Activated complex")([AC]) rarr underset("Product")(B) + underset("Catalyst")(C)`
The reaction proceeds through a new path with lower activation energy and hence is faster.
According to adsorption theory, transition metal provides a large surface are with free valencies on which the reactants are adsorbed. As a result , the concentration of the reactants on the surface increases and hence the rate increases.
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PRADEEP-D- AND F-BLOCK ELEMENTS-CONCEPTUAL QUESTIONS
  1. How is the variability in oxidation states fo transition metals differ...

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  2. Among lanthanoids, Ln (III) compounds are predominant. However, occasi...

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  3. How would you account for the fact that the transition metals and thei...

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  4. Why generally there is an increase in density of elements from titani...

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  5. Giving reasons indicate which one of the following would be coloured ?...

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  6. Scandium forms no coloured ions, yet it is regarded as a transition el...

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  7. A substance is found to have a magnetic moments of 3.9BM.How many unpa...

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  8. The paramagnetic character in 3d transition series elements increases ...

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  9. Decide giving reason which one of the following pairs exhibits the pr...

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  10. (a) of the ions Ag^(+),Co^(2+) and Ti^(+), which one will be coloured ...

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  11. Why are the ionisation energies of 5d elements greater than 3d element...

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  12. Describe giving reason which one of the following pairs has the proper...

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  13. Give reason for the following features of transition metal chemistry: ...

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  14. The 4d and 5d series of transition metals have more frequency metal-me...

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  15. Give reasons for each of the following: (i) Size of trivalent lantha...

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  16. Assign reason for each of the following statement: (i) The largest n...

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  17. (i) Which is a stronger reducing agent Cr^(2+) or Fe^(2+) and why ? ...

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  18. Assign reasons for each of the following : (i) Manganese exhibits th...

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  19. Explain why Zn shown only +2 oxidation state.

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  20. Why is first ionization enthalpy of Cu higher than that of Na ?

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