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How would you account for the following ...

How would you account for the following : (i) Many of the transition elements are virtually the same as those of the corresponding members of the second series.
(iii) There is a greater range of oxidation states among the actinoids than among the lanthanoids.

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There is a greater range of variable oxidation states among the actinoids than among the lanthanoids, Why ?

The atomic radii of the metals of the third (5d) series of transitions elements are virtually the same as those of the corresponding members of the second (4d) series. Explain.

How will you account for the following ? (i) The metallic radii of the third (5d) series of transition metals are virtually the same as those of the corresponding group members of the second (4d) series. (ii) Lanthanoids form primarily +3 ions while actinoids usually have higher oxidation states in their compounds . Among the lanthanoids, Ln(III) compounds are predominant. However, occasionally in solution or in solid state +2 and +4 ions are obtained. Explain.

How would you account for the following? (i) The atomic radii of the metals of the third (5d) series of transition elements are virtually the same as those of the corresponding member of the second (4d) serie (ii) Because oxygen and fluorine are highly electronegative elements and small in size.

How would you account for the following? (i) The atomic radii of the metals of the third (5d) series of transition elements are virtually the same as those of the corresponding member of the second (4d) serie (ii) The E^(@) value for the Mn^(3+)//Mn^(2+) couple is much more positive than that for Cr^(3+)//Cr^(2+) couple of Fe^(3+)//Fe^(2+) couple. (iii) The highest oxidation state of a metal is exhibited in its oxides or fluoride.

How would you account for the following? (i)The atomic radii of the metals of the third (5d) series of trasition elements are virtually the same as those of the corresponding members of the second (4d) series. (ii)The E^(@) value for the Mn^(3+)//Mn^(2+) couple is much more positive than that for Cr^(3+)//Cr^(2+) couple or Fe^(3+)//Fe^(2+) couple. (iii)The highest oxidation state of a metal is exhibited in itsoxide or fluoride.

PRADEEP-D- AND F-BLOCK ELEMENTS-ADDITIONAL QUESTIONS (SHORT ANSWER QUESTIONS )
  1. Name the gas evolved when concentrated HCI is added to powdered potass...

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  2. Write an equation in ionic form to represent the oxidizing actionof Cr...

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  3. Why Mn^(2+) compounds are more stable than Fe^(2+) compounds towards o...

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  4. Give the preparation of potassium permanganate from pyrolusite ore.

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  5. What happens when (i) KMnO(4) is heated (ii) K(2)Cr(2)O(7)is heated.

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  6. What happens when acidified KMnO(4)reacts with (i) H(2)S (ii)Oxalic ac...

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  7. Describe the oxidising property of KMnO(4) in neutral or faintly alkal...

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  8. What chemical changes take place when (i) MnO(2) is fused with KOH in ...

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  9. Write ionic equations for the conversion of (a)manganate to permanga...

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  10. Write chemical equations for the following reactions: (a) Oxidatio...

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  11. Complete the following chemical equations : (i) 8MnO(4)^(-)+3S(2)O(3...

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  12. What is meant by disproporitonation of an oxidation state? Give an exa...

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  13. What happens when (i) (NH(4))(2) Cr(2) O(7) is heated ? (ii) H(3)PO...

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  14. Complete the following equations : (i) 2MnO(4)^(-) + 16 H^(+) + 5S^...

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  15. What are inner-transition elements? Decide which of the following atom...

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  16. What is lanthanoid contraction? What is its cause and what ar its cons...

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  17. Misch metal is

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  18. How would you account for the following : (i) Many of the transition...

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  19. (a) How would you account for the following : (i) Actinoids contract...

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  20. Give reasons for the following: (i) Transition metals form alloys....

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