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A chemist has 4 samples of artificial sw...

A chemist has 4 samples of artificial sweetener, A,B,C and D. To identify these samples, he performed certain experiments and noted the following observations.
(i) A and D both form blue-violent colour with ninhydrin.
(ii) Lassaigne extract of C gives positive `AgNO_(3)` test and negative `Fe_(4)[Fe(CN)_(6)]_(3)` test.
(iii) Lassaigne extract of B and D gives positive sodium nitroprusside test.
Based on these observations which option is correct?

A

A:Alitame, B:Saccharin, C:Aspartame, D:Sucralose

B

A:Saccharin, B:Alitame , C:Sucralose, D:Sucralose

C

A:Aspartame, B:Saccharin, C:Sucralose, D:Alitame

D

A:Aspartame, B:Alitame, C:Saccharin,, D:Sucralose

Text Solution

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The correct Answer is:
c
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A, B, C and D are four artificial sweetners. (i) A and D give positive test with ninhydrin. (ii) C form precipitate with AgNO_3 in the lassaigne extract of the sugar. (iii) B and D give positive test with sodium nitroprusside. Correct option is:

In a Lassaigne's test for sulphur in the organic compound with sodium nitroprusside solution the purple colour formed is due to

Lassaigne's extract is botted with dilute HNO_(3) before testing for halogens because :

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