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AgNO(3)(aq.) was added to an aqeous KCl ...

`AgNO_(3)(aq.)` was added to an aqeous `KCl` solution gradually and the conductivity of the solution was measured. The plot of conductance `(Lambda)` versus the volume of `AgNO_(3)` is :

A

P

B

Q

C

R

D

S

Text Solution

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The correct Answer is:
D

As `AgNO_(3)`, is added to solution, KCl will be displaced according to following reaction
`AgNO_(3)(aq)+KCl (aq)toAgCl(s)+KNO_(3)(aq)`
for every mole of KCl displaced from solution, one mole of `KNO_(3)` comes in solution resulting in almost constant conductivity. as the end point is reached, added `AgNO_(3)` remain in solution increasing ionic concentration. hence conductivity increases.
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