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In SiF(6)^(2-) and SiCl(6)^(2-). which o...

In `SiF_(6)^(2-) and SiCl_(6)^(2-).` which one exist?

A

`SiF_(6)^(2-)` because of small size of F

B

`SiF_(6)^(2-)` because of large size of F

C

`SiCl_(6)^(2-)` because of small size of Cl

D

`SiCl_(6)^(2-)` because of large size of Cl

Text Solution

Verified by Experts

The correct Answer is:
A

`SiF_(6)^(2-)` is known due to the small size of F-atoms. The small 6 F-atom can be easily accommodated around Si-atom to form `SiF_(6)^(2-)` while in `SiCl_(6)^(2-)`, 6 large Cl-atoms cannot be accomodated around Si-atom.
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Explore conceptually related problems

iii. In SiF_6^(2-) and SiCl_6^(2-) , which one is known and why ?

Why [SiCl_(6)]^(-) cannot exist?

Assertion: SiF_(6)^(2-) is known but SiCl_(6)^(2-) is not. Reason: Size of fluorine is small and its lone pair of electrons intersects with d-orbitals of Si strongly.

Assertion SiF_(6)^(2-) anion exists but CF_(6)^(2-) does not Reasoning Si atom vacnat d-orbital while C-atom has not .

Statement-I: SiF_(6)^(-2) is known but SiCl_(6)^(-2) in not known Statement-II: Interaction of 'F' lone pair electrons with 'Si' is stronger than that of chlorine and due to smaller size of 'F' steric repulsion will bel less.

SiF_(6)^(2-) exist but not CF_(6)^(2-) explain why ?

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-PRACTICE SET 09-PAPER 1 (PHYSICS & CHEMISTRY)
  1. Cyclic trimer can be obtained as a polymerisation product by the carbo...

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  2. Which N-atom of cyanide species is more basic?

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  3. In SiF(6)^(2-) and SiCl(6)^(2-). which one exist?

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  4. In the temperature changes from 27^(@)C to 127^(@)C, the relative perc...

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  5. Dehydration of CH(3)-underset(OH)underset(|)(C)H-CH(2)-CH(3) is an aci...

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  6. Manufacture of acetic acid by fermentation process is called

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  7. The basicity of aniline is less than that of cyclohexylamine. This is ...

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  8. Coupling of diazonium salts of following takes place in the order

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  9. Proteins give white precipitate with Millon's regent, which is -

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  10. For the purification of organic compounds, the latest technique follow...

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  11. the ascending order of stability of the carbanion CH(3)(P),C(6)H(5)ove...

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  12. Which of the following is a pseudohalide?

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  13. pK(h) would be minimum for the salt

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  14. Among the following, the compound that can be most readily sulphonated...

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  15. Among the following sets of reactants which one produces anisole?

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  16. How many geometrical isomers of the compound [Pt(NH(3))(Br)(Cl)(Py)] w...

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  17. The product P formed in the following reaction sequence is Glucoseov...

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  18. CH(3)COOH+PCl(5)to'P', choose the correct option from the following

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  19. The plastic household crockery is prepared by using

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  20. Sodium benzoate is a commonly used foor preservative. It is

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