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The rate constants k(1) and k(2) for two...

The rate constants `k_(1)` and `k_(2)` for two different reactions are `10^(25)e^(-4000//T)` and `10^(25)e^(-1000//T)`, respectively. The temperature at which `k_(2)=k_(2)` is

A

`2000/2.303K`

B

`2000K`

C

`3000/2.303K`

D

`1000K`

Text Solution

Verified by Experts

The correct Answer is:
C

`k_(1)=10^(26)e^(-4000//T)`
`k_(2)=10^(25)e^(-1000//T)`
if `k_(1)=k_(2)`, then
`10^(26)e^(-4000//T)=10^(25)e^(-1000//T)`
or `ln_(10)-4000/T=-1000/T`
or `T=3000/2.303K`
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