For a reaction scheme `Aoverset(k_(1))toBoverset(k_(2))toD` , If the rate of formation if `B` is set to be Zero then the concentration of `B` is given by :
For a reaction scheme A overset ( k _ 1 ) to B overset ( k _ 2 ) to C , if the rate of formation of B is set to be zero then the concentration of B is given by :
Aoverset(K_(1))toBoverset(K_(2))toC if all the reaction are 1^(st) order and (d[B])/(dt)=0 . Determine [B].
Conisder parallel reaction: Aoverset(k_(1))rarrB, 2Aoverset(k_(2))rarrC+D What would be the rate expresison for [A] ?
If the rate of reaction between A and B is given by rate =k[A][B]^(2) , then the reaction is :
if the rate of reaction between A and B is given by rate =k[A] [B^(n)] then the reaction is
Mechanism of the reaction is: A overset(k_(1))rarrB, 2Aoverset(k_(2))rarr C + D What is (-d[A])/(dt) ?
Two consecutive irreversible fierst order reactions can be represented by Aoverset(k_(1))(rarr)Boverset(k_(2))(rarr)C The rate equation for A is readily interated to obtain [A]_(t)=[A]_(0).e^(-k_(1^(t))) , and [B]_(t)=(k_(1)[A]_(0))/(k_(2)-k_(1))[e^(-k_(1)^(t))-e^(-k_(2)^(t))] At what time will B be present in maximum concentration ?