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The number density of molecules of a gas...

The number density of molecules of a gas depends on their distance `r` from the origin as, `n(r)=n_(0) e^(- alpha r^(4))`. Then the total number of molecules is proportional to :

A

`n_(0) alpha^(-3//4)`

B

`sqrt(n_(0) alpha^(½)`

C

`n_(0) alpha^(a//4)`

D

`n_(0)alpha^(-3)`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the total number of molecules, \( N \), given the number density \( n(r) = n_0 e^{-\alpha r^4} \). The total number of molecules can be calculated by integrating the number density over the entire volume. ### Step-by-Step Solution: 1. **Understanding the Volume Element**: The volume element in spherical coordinates is given by: \[ dv = 4\pi r^2 dr \] 2. **Setting Up the Integral**: The total number of molecules \( N \) can be expressed as: \[ N = \int_0^\infty n(r) \, dv \] Substituting for \( n(r) \) and \( dv \): \[ N = \int_0^\infty n_0 e^{-\alpha r^4} (4\pi r^2) \, dr \] This simplifies to: \[ N = 4\pi n_0 \int_0^\infty r^2 e^{-\alpha r^4} \, dr \] 3. **Changing Variables**: To solve the integral \( \int_0^\infty r^2 e^{-\alpha r^4} \, dr \), we can use a substitution. Let: \[ u = \alpha r^4 \quad \Rightarrow \quad du = 4\alpha r^3 \, dr \quad \Rightarrow \quad dr = \frac{du}{4\alpha r^3} \] From the substitution, we have \( r^2 = \left(\frac{u}{\alpha}\right)^{\frac{1}{4}} \) and \( r^3 = \left(\frac{u}{\alpha}\right)^{\frac{3}{4}} \). 4. **Changing Limits**: When \( r = 0 \), \( u = 0 \) and when \( r \to \infty \), \( u \to \infty \). 5. **Substituting in the Integral**: The integral becomes: \[ \int_0^\infty r^2 e^{-\alpha r^4} \, dr = \int_0^\infty \left(\frac{u}{\alpha}\right)^{\frac{1}{4}} e^{-u} \frac{du}{4\alpha \left(\frac{u}{\alpha}\right)^{\frac{3}{4}}} \] Simplifying this gives: \[ = \frac{1}{4\alpha} \int_0^\infty \frac{u^{\frac{1}{4}}}{\alpha^{\frac{1}{4}}} e^{-u} \, du = \frac{1}{4\alpha^{\frac{3}{4}}} \int_0^\infty u^{\frac{1}{4}} e^{-u} \, du \] 6. **Using the Gamma Function**: The integral \( \int_0^\infty u^{\frac{1}{4}} e^{-u} \, du \) is related to the Gamma function: \[ \Gamma\left(\frac{5}{4}\right) = \int_0^\infty u^{\frac{1}{4}} e^{-u} \, du \] 7. **Final Expression for N**: Thus, we have: \[ N = 4\pi n_0 \cdot \frac{1}{4\alpha^{\frac{3}{4}}} \cdot \Gamma\left(\frac{5}{4}\right) \] This shows that \( N \) is proportional to \( n_0 \alpha^{-\frac{3}{4}} \). ### Conclusion: The total number of molecules \( N \) is proportional to: \[ N \propto n_0 \alpha^{-\frac{3}{4}} \]
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