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Hybridization of CH4

Hybridization of CH4

The Hybridization of CH4 (methane) involves sp³ hybrid orbitals on the carbon atom. This hybridization allows carbon to form four sigma bonds with four hydrogen atoms, resulting in a tetrahedral molecular geometry. Let’s learn this concept in detail.

1.0What is the Hybridization of CH4 (Methane)?

The hybridization of CH₄ (methane) is sp³. In methane, the carbon atom forms four sigma bonds with four hydrogen atoms. To accommodate these bonds, the carbon atom undergoes hybridization, leading to the formation of four equivalent sp³ hybrid orbitals. These orbitals then overlap with the 1s orbitals of the four hydrogen atoms, resulting in the tetrahedral molecular geometry of methane. Let’s understand hybridization of carbon in CH4 step by step - 

1. Electron Configuration of Carbon : 

Carbon's electron configuration is 1s22s22p2, indicating two electrons in the 1s orbital, two in the 2s orbital, and two in the 2p orbitals.

2. Valence Electrons : 

Carbon has four valence electrons. Methane forms four sigma bonds with four hydrogen atoms, requiring four orbitals to accommodate these bonds.

3. Orbital hybridization of CH4

Carbon undergoes hybridization to form four equivalent orbitals suitable for sigma bonding.

  • In methane, carbon undergoes sp³ hybridization, where one 2s orbital and three 2p orbitals combine to produce four sp³ hybrid orbitals.

Orbital hybridization of CH4

4. Formation of Sigma Bonds :

  • Each sp³ hybrid orbital on carbon overlaps with a 1s orbital on a hydrogen atom, resulting in the formation of four sigma (σ) bonds.
  • These sigma bonds are directed towards the corners of a tetrahedron, giving methane a tetrahedral molecular geometry.

5. Tetrahedral Molecular Geometry :

  • The four sigma bonds and their associated hydrogen atoms arrange themselves tetrahedrally around the carbon atom.
  • The bond angles in methane are approximately 109.5 degrees, reflecting the tetrahedral arrangement of the bonds.

2.0Important Properties of Methane (CH₄) 

Methane (CH₄) is a simple hydrocarbon with essential properties, and a summary of Hybridization of CH₄ :

Chemical Formula

CH₄

Molecular Shape

Tetrahedral

Bond Angles

109.5 degrees

Hybridization of Carbon

sp³

Type and Nature of Bonds

Four sigma, Covalent 

Physical State

colorless and odorless gas

Melting Point

−182.5 0C

Boiling Point

−161.5 0C

Frequently Asked Questions

In CH4, the sp3 hybrid orbitals are equivalent and symmetrically arranged in space to form a tetrahedral geometry. Each orbital points to a corner of a tetrahedron, with bond angles of approximately 109.5 degrees between them, optimizing the spatial arrangement to minimize electron pair repulsion.

sp3 hybridization of CH4 allows carbon to form four sigma bonds with four hydrogen atoms, resulting in a tetrahedral molecular geometry.

The bond angles in methane are approximately 109.5 degrees. This tetrahedral angle results from the arrangement of four equivalent sigma bonds around the central carbon atom.

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