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Assertion : Alkyl isocyanides in acidifi...

Assertion : Alkyl isocyanides in acidified water give alkyl formamides.
Reason : In isocyanides, carbon first act as a nucleophile and then as electrophile.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Text Solution

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The correct Answer is:
A

In an isocyanide, first an electrophile and then a nucleophile add at the carbon to form a species which usually undergoes further transformations.
`Roverset(+)(N)equiv bar(C )+E^(+)rarrR overset(+)Nequiv CE overset(Nu)rarrRN equiv C(Nu)E`
`Roverset(+)(N)equiv bar(C )+H_(2)OrarrRNequiv CHOHrarrunderset("alkyformamide")(RNHCHO)`
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