Home
Class 12
CHEMISTRY
CsBr crystallizes in a body-centred cubi...

`CsBr` crystallizes in a body-centred cubic unit lattice with an edge length of `4.287 Å`. Calculate the angles at which the second-order reflection maxima may be expected for `(2, 0, 0)`, `(1, 1, 0)`, planes when `X`-rays of `gamma = 0.50 Å` are used.

Text Solution

Verified by Experts

For `bc c` lattice, `d_(200) = a//2`
So, for second-orderreflection, `2gamma = 2 xx (a)/(2) sin theta_(1)`
or `sin theta_(1) = (2gamma)/(a)`
i.e., `sin theta_(1) = (2 xx 0.50)/(4.287)` and `theta_(1) = 13^(@)29'`
`d_(110) = (a)/(sqrt2)`
So, `2 gamma = 2 xx (a)/(sqrt2) sin theta_(2) = (sqrt2gamma)/(a)`.
`sin theta_(2) = (sqrt2 xx 0.50)/(4.284) implies theta_(2) = 9^(@)30'`
`d_(111) = (a)/(2sqrt3)`, so `2gamma = 2 xx (a)/(2sqrt3) sin theta_(3) implies sin theta_(3) = (2sqrt3gamma)/(a)`
i.e., `sin theta_(3) = (2 xx sqrt3 xx 0.50)/(4.287)` and `theta_(3) = 23^(@)49'`
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    CENGAGE CHEMISTRY|Exercise Solved Examples|13 Videos
  • SOLID STATE

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehension)|13 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY|Exercise SUBJECTIVE TYPE|3 Videos
  • SOLUTIONS

    CENGAGE CHEMISTRY|Exercise Ex 2.3 (Objective)|9 Videos

Similar Questions

Explore conceptually related problems

A metal crystallizes in a body centred cubic lattice (bcc) with the edge of the unit cell 5.2Å . The distance between the next nearest neighbour is:

Calcium crystallizes in a face centred cubic unit cell with a = 0.556 nm. Calculate the density if it contains (i) 0.1 % Frenkel defect (ii) 0.1 % Schottky defect

A metal crystallizes in a face centred cubic unit cell with a = 0.560 nm . Calculate the density of the metal if it contains 0.1% Schottky defects. (Atomic mass of metal = 40 g mol^(-1))

Calcium crystallizes in a face centred cubic unit cell with a = 0.560 nm. The density of the metal if it contains 0.1% schottky defects would be:

An element (density 7.2 g cm^(-3)) crystallizes in a body centred cubic structure having its unit cell edge length 2.88 Å . Calculate the number of atoms present in 156 g of the element.