Home
Class 11
CHEMISTRY
0.002 gm of an organic compound was trea...

0.002 gm of an organic compound was treated according to Kjeldahl's method. `0.2xx10^-4` mol of `H_2SO_4` was required to neutralise `NH_3`. Calculate the percentage of `N_2`

Text Solution

Verified by Experts

m. mole of `H_2SO_4=0.2xx10^-4xx10^3=0.2xx10^-1`
mEq. Of `H_4SO_4=0.2xx10^-1xx2=0.4xx10^-1=0.04`
Percentage of `N_2`
`=(1.4xx"mEq. Of acid used to neutralise "NH_3)/("weight of compound")`
`=(1.4xx0.04)/(0.002)=28%`
Promotional Banner

Topper's Solved these Questions

  • PURIFICATION OF ORGANIC COMPOUNDS AND QUALITATIVE AND QUANTITATIVE ANALYSIS

    CENGAGE CHEMISTRY|Exercise SOLVED EXAMPLES|17 Videos
  • PURIFICATION OF ORGANIC COMPOUNDS AND QUALITATIVE AND QUANTITATIVE ANALYSIS

    CENGAGE CHEMISTRY|Exercise Subjective Type|11 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exercises (Archives )Subjective|4 Videos
  • REDOX REACTIONS

    CENGAGE CHEMISTRY|Exercise Archives (Integers)|1 Videos

Similar Questions

Explore conceptually related problems

Estimation of Nitrogen: There are two methods for the estimation of nitrogen (1) Dumas method and (2) Kjedahl's method. (1) Duma's method: A known mass of compound is heated with copper oxide (CuO) in an atmosphere of CO_(2) , which gives free nitrogen along with CO_(2) and H_(2)O . C_(x)H_(y)N_(z)+(2x+(y)/(2))CuO rarr xCO_(2) +(y)/(2)(H_(2)O)+(z)/(2)+(2x+(y)/(2))Cu. The gaseous mixture is passed over a heated copper gauze which converts traces of nitrogen oxides formed of N_(2) .The gaseous mixture is collected over an aqueous solution of KOH which absorbs CO_(2) and nitrogen is collected in the upper part of the graduated tube. (2) kjeldahl's method: A known mass of organic compound (0.5 gm) is mixed with K_(2)SO_(4) (10 gm) and CuSO_(4) (1.0 gm) or a drop of mercury (Hg) and conc. H_(2)SO_(4) (25 ml) , and heated in Kjeldahl's flask. CuSO_(4) or Hg acts as a catalyst , while K_(2)SO_(4) raises the boiling point of H_(2)SO_(4) . The nitrogen in the organic compound is quantitatively converted to ammonium sulphate . The resulting mixture is then distilled with excess of NaOH solution and the NH_(3) evolved is passes into a known but excess volume of standard HCl or H_(2)SO_(4) . The acid left unused is estimated by titration with some standard alkali . The amound of acid used against NH_(3) can thus be known and from this the percentage of nitogen is calculated. (a) C+H +S underset(H_(2)SO_(4))overset("conc.")rarr CO_(2) + H_(2)O +SO_(2) (b) N underset(H_(2)SO_(4))overset("conc.")rarr (NH_(4))_(2)SO_(4) (c) (NH_(4))_(2)SO_(4)+2NaOH rarr Na_(2)SO_(4)+2NH_(3) + 2H_(2)O (d) 2NH_(3) + H_(2)SO_(4) rarr (NH_(4))_(2)SO_(4) (3) This method is not applicable to compounds containing N in nitro and azo groups,and N persent in the ring (e.g., pyridine as N of these conpounds does not change to (NH_(4))_(2)SO_(4) (ammonium sulphate ) under these reaction condition. 0.002 gm of an organic compound was treated according to Kjeldahl's method . 0.2 xx 10^(-4) mol of H_(2)SO_(4) was required to neutralise NH_(3) . Calculated the percentage of N.

0.04gm of an organic compound was treated according to Kjeldahl's method. 0.6xx10^(-3) mol of H_(2)SO_(4) was required to neutralise NH_(3) .What will be the percentage of N in the given organic compound?

0.02gm of an organic compound was treated according to kjeldahl's method. 0.1xx10^(-4) mol of H_(2)SO_(4) was required to neutralise NH_(3) .The percentage of N_(2) is

Estimation of Nitrogen: There are two methods for the estimation of nitrogen (1) Dumas method and (2) Kjedahl's method. (1) Duma's method: A known mass of compound is heated with copper oxide (CuO) in an atmosphere of CO_(2) , which gives free nitrogen along with CO_(2) and H_(2)O . C_(x)H_(y)N_(z)+(2x+(y)/(2))CuO rarr xCO_(2) +(y)/(2)(H_(2)O)+(z)/(2)+(2x+(y)/(2))Cu. The gaseous mixture is passed over a heated copper gauze which converts traces of nitrogen oxides formed of N_(2) .The gaseous mixture is collected over an aqueous solution of KOH which absorbs CO_(2) and nitrogen is collected in the upper part of the graduated tube. (2) kjeldahl's method: A known mass of organic compound (0.5 gm) is mixed with K_(2)SO_(4) (10 gm) and CuSO_(4) (1.0 gm) or a drop of mercury (Hg) and conc. H_(2)SO_(4) (25 ml) , and heated in Kjeldahl's flask. CuSO_(4) or Hg acts as a catalyst , while K_(2)SO_(4) raises the boiling point of H_(2)SO_(4) . The nitrogen in the organic compound is quantitatively converted to ammonium sulphate . The resulting mixture is then distilled with excess of NaOH solution and the NH_(3) evolved is passes into a known but excess volume of standard HCl or H_(2)SO_(4) . The acid left unused is estimated by titration with some standard alkali . The amound of acid used against NH_(3) can thus be known and from this the percentage of nitogen is calculated. (a) C+H +S underset(H_(2)SO_(4))overset("conc.")rarr CO_(2) + H_(2)O +SO_(2) (b) N underset(H_(2)SO_(4))overset("conc.")rarr (NH_(4))_(2)SO_(4) (c) (NH_(4))_(2)SO_(4)+2NaOH rarr Na_(2)SO_(4)+2NH_(3) + 2H_(2)O (d) 2NH_(3) + H_(2)SO_(4) rarr (NH_(4))_(2)SO_(4) (3) This method is not applicable to compounds containing N in nitro and azo groups,and N persent in the ring (e.g., pyridine as N of these conpounds does not change to (NH_(4))_(2)SO_(4) (ammonium sulphate ) under these reaction condition. 0.50 gm of an organic compound was treated according to Kjedahl's method . The ammonia evolved was absorbed in 50 ml of (M)/(2) NaOH solution. Find the percentage of nitrogen in the compound.

A sample of 0.50 gm of an organic compound was treated according to Kjeldahl's method the smmonia evolved was absorbed in 50 ml of 0.5MH_2SO_4 . The residual acid required 60 cm of 0.5M solution of NaOH for neutralisation. Find the percentage composition of nitrogen in the compound.

0.50 gm of an organic compound was treated according to Kjeldahl's meghod. The ammonia evolved was absorbed in 50 ml of 0.5 MH_2SO_4 . The residual acid required 60 ml of (M)/(2)NaOH solution. Find the percentage of nitrogen in the compound.

0.4 gm of an organic compound was treated according to Kjeldahl's method. The ammonia evoled was absorbed in 50 ml or 0.5MH_3PO_3 . The residual acid required 30 ml of 0.5MCa(OH)_2 Find the percentage of N_2 in the compound.