Home
Class 12
CHEMISTRY
If the crystallises in zinc blende struc...

If the crystallises in zinc blende structure with `I^-` ions at lattice points. What fraction of tetrahedral voids is occupied by `Ag^+` ions ?

A

0.25

B

0.5

C

1

D

0.75

Text Solution

Verified by Experts

The correct Answer is:
B

In Agl crystals , number of `Ag^+` ions are equal to `I^-` ions . However , the number of tetrahedral voids are twice the number of atoms forming the cubic lattice .
`therefore` Number of tetrahedral voids occupied by `Ag^+` ions = 50%
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise EXERCISE 2|38 Videos
  • SOLID STATE

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|12 Videos
  • SOLID STATE

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|12 Videos
  • S-BLOCK ELEMENTS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise Exercise 2|20 Videos
  • SOLUTIONS AND COLLIGATIVE PROPERTIES

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|25 Videos

Similar Questions

Explore conceptually related problems

In Zinc blende , the percentage of tetrahedral voids occupied by Zn^(2+) ions is :

AgI crystallises in a cubic close-packed ZnS structure. What fraction of tetrahedral sites is occupied by Ag^(+) ions ?

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-SOLID STATE-EXERCISE 1
  1. At the limiting value of radius ration (r^+)/(r^-)

    Text Solution

    |

  2. The NaCl structure can be converted into CsCl structure

    Text Solution

    |

  3. If the crystallises in zinc blende structure with I^- ions at lattice ...

    Text Solution

    |

  4. In which pair most efficient packing is present?

    Text Solution

    |

  5. In which of the following packing 74% space is occupied by the atoms w...

    Text Solution

    |

  6. When the centres of the four immediate neighbouring spheres are joine...

    Text Solution

    |

  7. If the number of close packed sphere be N, then the number of octahedr...

    Text Solution

    |

  8. While placing the second layer over that first layer , if the sphere o...

    Text Solution

    |

  9. In an antiflourite structure, cations occupy

    Text Solution

    |

  10. The numbers of tetrahedral and octahedral holes in a ccp array of 100 ...

    Text Solution

    |

  11. The total number of octahedral void (s) per atom present in a cubic cl...

    Text Solution

    |

  12. Total no. of voids in 0.5 mole of a compound forming hexagonal closed ...

    Text Solution

    |

  13. Point out the correct statement for the set of characteristics of ZnS ...

    Text Solution

    |

  14. In which of the following crystals, alternate tetrahedral voids are oc...

    Text Solution

    |

  15. The ionic radii of Rb^(+) and I^(-) are 1.46 and 2.16Å. The most proba...

    Text Solution

    |

  16. A solid is formed by two elements P and Q . The element Q forms cubic ...

    Text Solution

    |

  17. Match the following

    Text Solution

    |

  18. The cubic unit cell of a metal (molar mass= 63.55 "mol"^(-1)) has an e...

    Text Solution

    |

  19. Xenon crystallizes in the face-centred cubic lattice and the edge of t...

    Text Solution

    |

  20. How many unit cells are present in a cube-shaped crystal of NaCl of ma...

    Text Solution

    |