Home
Class 11
CHEMISTRY
LiH, LiF and Li(3)N show exceptional th...

LiH, LiF and `Li_(3)N` show exceptional thermal stabilites. Comment.

Text Solution

Verified by Experts

`Li^(o+)` ion has very small size and has an exceptionally high charge to radius ratio and therefore salts of `Li^(o+)` ion with small anions viz. `H^(Θ)` , `F^(Θ)` and `N^(3-)` are highly stable due to their high lattice energy.
`U prop (1)/(r^(o+)+r_(Θ))`
Thus LiH, LiF and `Li_(3)N` show exceptionally high thermal stability.
Promotional Banner

Topper's Solved these Questions

  • S-BLOCK GROUP 1 - ALKALI METALS

    CENGAGE CHEMISTRY|Exercise Solved Examples|11 Videos
  • S-BLOCK GROUP 1 - ALKALI METALS

    CENGAGE CHEMISTRY|Exercise Ex 4.1 (Subjective)|24 Videos
  • REDOX REACTIONS

    CENGAGE CHEMISTRY|Exercise Archives (Integers)|1 Videos
  • S-BLOCK GROUP 2 - ALKALINE EARTH METALS

    CENGAGE CHEMISTRY|Exercise Ex 5.1 Objective|2 Videos

Similar Questions

Explore conceptually related problems

The following compounds have been arranged in the order of their increasing thermal stabilities. Identify the correct order. K_(2)CO_(3)(I),Na_(2)CO_(3)(II),Rb_(2)CO_(3)(III),Li_(2)CO_(3)(IV)

Assertion (A): Na_(2)CO_(3) and Li_(2)CO_(3) are thermally stable. Reason (R ): Both the carbonates are salts of large cations and large anions.

which of the following statement is not correct? (A) All alkali-metals salts impart a characteristic colour to the Bunsen flame. (B) The correct order of increasing thermal stability of the carbonates of alkali metals is Li_(2)CO_(3) (C) Among the alkali metal's cesium is the most reactive. (D) The reducing character of the alkali metal hydrides follow the order: "LiH>NaH>KH>RbH>CsH" ."]

Show that if three slabs of thermal resistance R_(1), R_(2) and R_(3) are placed in contact, the thermal resistance of the compound slab is given by R=R_(1)+R_(2)+R_(3) .

Salt of Li^(o+) with larger anions CO_(3)^(2-), NO_(3)^(Θ) are relatively less stable than its salts with small anions. Comment.