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Five isomeric p-subsituted aromatic comp...

Five isomeric p-subsituted aromatic compounds (A) to (E ) with molecular formula `C_(8)H_(8)O_(2)` are given for identifyication. Based on the following observition, give the strucctures of the compounds.
i. Both (A) and (B) form a silver mirror with Tollens reagent, (B) also gives a positive test with neutral `FeCl_(3)` solution.
ii. (C ) gives positive iodoform test.
iii. (D) is readily extracted in aqueous `NaHCO_(3)` solution.
iv. (E ) on acid hydrolysis gives 1,4-dihydroxy benzene.
Compound (D) is:

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
B

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Five isomeric p-subsituted aromatic compounds (A) to (E ) with molecular formula C_(8)H_(8)O_(2) are given for identifyication. Based on the following observation, give the structures of the compounds. i. Both (A) and (B) form a silver mirror with Tollens reagent, (B) also gives a positive test with neutral FeCl_(3) solution. ii. (C ) gives positive iodoform test. iii. (D) is readily extracted in aqueous NaHCO_(3) solution. iv. (E ) on acid hydrolysis gives 1,4-dihydroxy benzene. Compound (A) is:

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Given are the isomers of C_(8)H_(8)O_(2) . Which isomer gives positive iodoform test?