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overset((i)Mg//ether(ii)PhCHO)underset((...

`overset((i)Mg//ether(ii)PhCHO)underset((iii)H_(3)O^(+))rarr` Products

A

B

C

Both

D

None

Text Solution

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The correct Answer is:
C
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In the sequence of reactions C_(6)H_(5)Broverset(Mg)underset("ether")rarr (X) overset((i)CO_(2))underset((iii)H_(3)O^(+))rarr(Y) the product (Y) is

Identify X, Y and Z in the following synthetic scheme and write their structures. The product Z when treated with HBr gives compound A which on reductive ozonolysis gives formaldehyde as one of the product. Deduce the entire scheme. CH_(2)=CH-Br overset("(i) Mg/ ether")to X overset((ii)CO_(2))underset((iii) H_(3)^(+)O)toY overset(LiAlH_(4))to Z overset(HBr)toA overset(O_(2)//H_(2)O // Zn)to HCHO + other product

H-overset(O)overset(||)C-overset(O)overset(||)C-Hoverset(CH_(3)MgBr(excess))underset(H_(3)^(⊕)O)rarr Product :

overset((i)CH_(3)CHO)underset((ii)H_(3)O^(+))rarr (A) overset(HBr)rarr (B) The compounds (A) and (B)

Propene overset(HBr)rarr A overset((i)"Mg/ether")underset((ii)H_(2)O //"Boil")rarr B In the above sequence of reactions B is

Complete the following reactions: a. overset (Benzen e) underset ((A)) overset (Ac_(2)O) underset (+AICI_(3)) rarr (B) overset ((i) MeMgBr) underset ((ii) H_(3)O^((+))) rarr (C) overset (Conc.) underset (H_(2)SO_(4)) (D) overset (1. BH_(3)//THF) underset (2. H_(2)O_(2)//O^((-))H) rarr (E) b. overset (MeCH_(2)Br) underset ((A)) overset (alc.) underset (KOH) rarr (B) overset (Br_(2)) rarr (C) overset (2NaNH_(2)) rarr (D) overset (RMgBr) underset (1 mol) rarr RH + (E) overset (1. Acetone) underset (2. H_(3)O^((+))) rarr (F) c. overset (A1c.) underset (KOH) rarr (B) overset (NBS) rarr (C) overset (Mg..ether) rarr (D) overset (1. Acet on e) underset (2. H_(3)O^((+))) rarr (E) overset (conc. H_(2)SO_(4)) underset (Delta) rarr (F)

CENGAGE CHEMISTRY-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Exercises Single Correct
  1. Give the decreasing order of the following in the extent of hydration ...

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  2. Give decreasing order of the following towards NA reaction. I. I...

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  3. overset((i)Mg//ether(ii)PhCHO)underset((iii)H(3)O^(+))rarr Products

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  4. When CH(3)CHO is reacted in the presence of a base with excess of HCHO...

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  5. How will you distinguish the products proucts obtained by acidic hydro...

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  6. Give the decreasing order of hydrate formation of the following. I. ...

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  7. Ketone (A) overset(NH(2)OH.HCl)rarr (B) overset(H^(o+))rarr The k...

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  8. Aldehyde (A) overset(NH(2)OH.HCl)rarr (B) overset(H^(o+))rarr Me NH(2)...

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  9. Which oxime on acetylation followed by reaction with Na(2)CO(3) would ...

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  10. Compounds (B) and (C ), respectively, are:

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  11. overset(NaNO(2)+HCI)rarr (B) overset((i)Ac(2)O)underset((ii)H(2)O^(o+)...

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  12. Me - -=-H overset(NaNH(2))underset(+liq.NH(3))rarr (C ) overset(H(3)O^...

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  13. Compound (B) is:

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  14. overset("High conc. of base")rarr ? + ? The products are:

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  15. The products are:

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  16. For the Cannizzaro reaction in which of the following statements is tr...

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  17. For the Cannizzaro reaction in which of the statement is true regardin...

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  18. Two moles of HCHO and 1 mol of PhCHO react with conc. NaOH. What are t...

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  19. Two moles of HCHO and 1 mol of PhCHO react with conc. NaOH. What are t...

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  20. Identify the following disproportionation reaction. I. 2H-overset(D)...

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