Home
Class 12
CHEMISTRY
Which of the following is not the mechan...

Which of the following is not the mechanism of Cannizzaro reaction when the concentration of base is very high ?
`2HCHO overset("High conc.")underset("of base")rarr HCOO^(Θ)+CH_(3)O^(Θ)`

A

The attack of `overset(Θ)(OH)` at the `(C=O)` group.

B

Removal of `H^(o+)` ion by the `O^(Θ)H` ion form `(underset(OH)underset(|)CH_(2)-O^(Θ))`.

C

The transfer of `H^(Θ)` ion to the `(C=O)` group of another `HCHO`.

D

The abstraction of proton from the carboxylic acid.

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY|Exercise Exercises Assertion-Reasoning|10 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY|Exercise Archives Objective|10 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY|Exercise Exercises Multiple Correct|40 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY|Exercise Archives Analytical And Descriptive|15 Videos
  • AMINES

    CENGAGE CHEMISTRY|Exercise QUESTION BANK|1 Videos

Similar Questions

Explore conceptually related problems

Which of the following is not the mechanism of Cannizzaro reaction ? 2PhCHO overset(overset(Θ)(OH))rarr PhCH_(2)OH+PhCOO^(Θ)

overset("High conc. of base")rarr ? + ? The products are:

Which one of the following is not an intermediate in the generally accepted mechanism for the reaction shown below? CF_(3)overset(O)overset(||)(C)OH+CH_(3)underset(OH)underset(|)(CH)CH_(3) overset(H_(2)SO_(4))rarr CF_(3)overset(O)overset(||)(C)Ounderset(CH_(3))underset(|)(CH)-CH_(3)+H_(2)O

Which of the following compounds is prduced when this reaction takes place ? H_(3)C-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-O-CH_(3)overset(HI)underset(coid)rarr

Write the mechanism of the following reaction : 2CH_(3) CH_(2) OH underset("413K")overset("Conc. "H_(2)So_(4))rarr CH_(3) CH_(2) - O - CH_(2) - CH_(3)

Which of the following are crossed aldol products in the given reaction ? MeCHO+MeCH_(2)overset(overset(Θ)(OH))underset(25^(@)C)rarr

In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH)rarrPh-CH_(2)OH+PhCO_(2)^(-) the slowest step is:

CENGAGE CHEMISTRY-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Exercises Single Correct
  1. The final product (E ) in the following reaction is:

    Text Solution

    |

  2. Which of the following is not the mechanism of Cannizzaro reaction ? ...

    Text Solution

    |

  3. Which of the following is not the mechanism of Cannizzaro reaction whe...

    Text Solution

    |

  4. Clemmensen's reduction will convert cyclohexanone into:

    Text Solution

    |

  5. CH-=CH overset(H(g)SO(4))underset(H(2)SO(4))rarr (X) overset(LiAIH(4))...

    Text Solution

    |

  6. Ethylidene chloride is hydrolysed with aqueous NaOH. The product forme...

    Text Solution

    |

  7. The vapours of ethyl alcohol are passed over red hot copper at 573 K t...

    Text Solution

    |

  8. (CH(3))(2)CHOH overset("Mild")underset("oxidation[O]")rarr (X) overset...

    Text Solution

    |

  9. The chemical reaction of acetaldehyde and ammonia results in:

    Text Solution

    |

  10. Which of the following ketone will not give yellow precipitate with Na...

    Text Solution

    |

  11. Which is the Wacker process ?

    Text Solution

    |

  12. 2-Propanone (acetone) can be obtained by Wacker's process starting wit...

    Text Solution

    |

  13. When diethyl cadmium [(C(2)H(5))(2)Cd] is treated with acetyl chloride...

    Text Solution

    |

  14. The following reaction is an example of: RCHOHR'+CH(3)COCH(3) overse...

    Text Solution

    |

  15. Which of the following reagents can give Urotropine, which is used as ...

    Text Solution

    |

  16. The reaction between carbonyl compound and alpha-bromoesters in the pr...

    Text Solution

    |

  17. Name the following reaction. C(6)H(5)-C-=N overset(SnCl(2)+HCl)rarr ...

    Text Solution

    |

  18. Name the following reaction. PhCHO+CH(2)(COOEt)(2)overset((i) "Pyrid...

    Text Solution

    |

  19. A compound has molecular formula C(6)H(12)O. It does not reduce Tollen...

    Text Solution

    |

  20. A substance C(5)H(10)O does not reduce Fehling's solution, forms a phe...

    Text Solution

    |