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Compound (A) (C(6)H(12)O(2)) on reductio...

Compound (A) `(C_(6)H_(12)O_(2))` on reduction with `LiAlH_(4)` yielded two compounds (B) and (C ). The compound (B) on oxidation gave (D), which on treatment with aqueous alkail and subsequent heating furnished (E ). The latter on catalytic hydrogenation gave (C ). The compound (D) was oxidised further to give (F) which was found to be a monobasic acid (molecular formula weight `= 60.0`). Deduce the structures of (A), (B), (C ), (D), and (E ).

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A compound (A) on oxidation gives B (C_(2)H_(4)O_(2)) . (A) also reacts with dil. NaOH and on subsequent heating forms (C). The compound (C) on catalytic hydrogenation gives (D). Identify A, B, C, D and write down the reactions involved.

An organic compound (A) (C_(6)H_(10)O) on reaction with CH_(3)MgBr followed by acid treatment gives compound (B). The compound (B) on ozonolysis gives compound (C ), which in the presence of a base gives 1-acetyl cyclopentane (D). The compound (B) on reaction with HBr gives compound (E ). Write the structures of (A), (B), (C ), (D), and (E ). Show how (D) is formed from (C ).

CENGAGE CHEMISTRY-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Archives Subjective
  1. In what manner the following transformation might be carried out (in n...

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  2. Complete the following with appropriate structures.

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  3. Compound (A) (C(6)H(12)O(2)) on reduction with LiAlH(4) yielded two co...

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  4. Arrange the following in the increasing order of expected enol content...

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  5. Write the structure of major organic product expected from the followi...

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  6. How will you bring about the following conversions ? '4-nitrobenzaldeh...

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  7. Complete the following reaction with appropriate structure. C(6)H(5)...

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  8. Complete the following reaction with appropriate structure:

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  9. Suggest appropriate structure of the missing compounds. (The number of...

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  10. Complete the following, giving the structures of principal organic pro...

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  11. Acetophenone on reaction with hydroxyl amine hydrochloride can produce...

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  12. An aldehyde (A) (C(11)H(8)O), which does not undergo self aldol conden...

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  13. Complete the following reactions with appropriate structures of produc...

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  14. Compound (A) (C(8)H(8)O) on treatment with NH(2)OH.HCl gives (B) and (...

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  15. o-Hydroxy benzaldehyde is more soluble in water than p-hybroxy benzald...

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  16. Carry out the following transformation in not more than three steps. ...

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  17. What would be the major product in the following reaction ?

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  18. An organic compound (A) (C(6)H(10)O) on reaction with CH(3)MgBr follow...

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  19. Identify (A), (B), (C ), (D), and (E ) in the following reactions and ...

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  20. (C(6)H(12))overset(HCl)rarr underset((C(6)H(13)Cl))(B)+(C ) (B)overs...

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