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Consider the following reactions: W...

Consider the following reactions:

Which of the following reagents is/are used in the above conversion?

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
C, D

A `implies` The protection of

group by

(because it gives a six-membered ring). If the protection of

group is carried out by

it would give a five-membered ring (cyclic ketal).
B `implies` Ester is converted to `(RHO+R'OH)`. It can be carried out by `LAH//"ether", H_(3)O^(+)` or by `B_(2)H_(6)//THF`.
C `implies 1^(@)` Alcohol is converted to aldehyde and is carried out by `PC C` or by Jones reagent `(H_(2)CrO_(4)+"aq. acetone")`.
`D implies` Aldehyde is converted to alkane by Clemmensen's `(Zn-Hg//HCl)` or by Wolff-Kishner reduction `(PhNHNH_(2)+ glycol+ KOH)`.
`E implies` Cyclic ketal is hydrolysed to give back ketone. So the answers are `(c )` and `(d)`
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CENGAGE CHEMISTRY-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Multiple Correct)
  1. Which statement(s) is/are correct about the reaction:

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  2. Which statement(s) is/are correct?

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  3. Consider the following reactions: Which of the following reagents...

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  4. In Q. No. 3, direct conversion of II to V can be carried by:

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  5. Consider the following reactions: Which of the following group(s)...

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  6. Compound C(4)H(8)O(2) exists in various strutures as shown: Whic...

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  7. Consider the following Baeyer-Villiger oxidation.

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  8. Select the correct Baeyer-Villiger oxidation reaction:

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  9. Select the correct group(s) of reagent(s) used in the following conver...

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  10. Which statements(s) is//are correct:

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  11. Which of the following statement(s) is/are correct?

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  12. In Q.No. 11, which of the following reagents can be used to convert (A...

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  13. Which of the following will give yellow precipitate with KOI?

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  14. Which of the following will undergo periodic oxidation?

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  15. Which of the following reactions is//are correct?

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  16. Which of the following reactions is//are correct?

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  17. Which statement(s) is/are wrong?

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  18. Which of the following reaction(s) is/are correct?

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  19. Which of the following reaction(s) is/are wrong?

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  20. Which of the following reactions is/are wrong?

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