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Consider the following reactions: W...

Consider the following reactions:

Which of the following group(s) of reagents is/are used in the above conversion?

A

a.`(A) implies "Acidic" KMnO_(4), (B) implies Ca(OH)_(2)`,
`(C ) implies Zn-Hg//HCl`

B

b.`(A) implies O_(3)//Ph_(3)P, (B) implies Ba(OH)_(2), (C ) implies LAH//"ether"`

C

c.`(A) implies O_(3)//H_(2)O, (B) implies Sr(OH)_(2)`,
`(C ) implies NH_(2)NH_(2)//overset(ɵ)(O)H`

D

d.`(A) implies O_(3)//Ag_(2)O, (B) implies Ba(OH)_(2), (C ) implies HI+"Red" P`

Text Solution

Verified by Experts

The correct Answer is:
A, C, D

A `implies` The oxidation of `(C=C)` to acids can be carried out by either of the following: (i) acidic `KMnO_(4)`, (ii) ozonolysis following by hydrolysis `(O_(3)//H_(2)O)`, (iii) ozonolysis followed by oxidation with `Ag_(2)O, H_(2)O_(2)`, peracid, or `KMnO_(4)//NaIO_(4)`
B `implies` (II) is converted to Ca, Ba, or Sr salt by reacting with their hydroxides which on dry distillation or heating gives cyclic ketone with one `C` atom less than in II.

`C implies` The

group can be converted to `(-CH_(2)-)` by either of the following:
i. Clemmensen's reduction `(Zn-Hg//HCl)`,
ii. Wolff-Kishner reduction `(NH_(2)NH_(2)+overset(ɵ)(O)H)`, or
iii. `HI+P`
So the answer are `(a)`, `(c )`, and `(d)`.
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CENGAGE CHEMISTRY-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Multiple Correct)
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  2. In Q. No. 3, direct conversion of II to V can be carried by:

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  5. Consider the following Baeyer-Villiger oxidation.

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  6. Select the correct Baeyer-Villiger oxidation reaction:

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  7. Select the correct group(s) of reagent(s) used in the following conver...

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  8. Which statements(s) is//are correct:

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  9. Which of the following statement(s) is/are correct?

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  10. In Q.No. 11, which of the following reagents can be used to convert (A...

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  11. Which of the following will give yellow precipitate with KOI?

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  12. Which of the following will undergo periodic oxidation?

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  13. Which of the following reactions is//are correct?

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  14. Which of the following reactions is//are correct?

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  15. Which statement(s) is/are wrong?

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  16. Which of the following reaction(s) is/are correct?

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  17. Which of the following reaction(s) is/are wrong?

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  18. Which of the following reactions is/are wrong?

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  19. Which of the following unbalanced reactions is/are correct?

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  20. Which of the following methods is/are correct for the synthesis of ben...

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