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Which of the following will give yellow ...

Which of the following will give yellow precipitate with KOI?

A

a.Cyclopentyl methyl carbinol

B

b.`alpha`-Phenyl ethanol

C

c.`A AE`

D

d.`I_(3)C-CHO`

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

Methanol is also called carbinol.
a.
b. `Moverset(beta)(e)-underset(Ph)underset(|)overset(alpha)(CH)-OH` (It also contains `(Me-underset(OH)underset(|)(CH)-)` group and gives the iodoform test.)
c. Although `A AE` (acetoacetic easter)

contains `(Me-overset(O)overset(||)(C )-)` group, due to its existence in enolic form

it does not give the iodoform test.
d. `(I_(3)C-CHO)`, this is one of the intermediate products formed in the iodoform reaction, so it gives iodoform test.

So the answers are `(a)`, `(b)`, and `(d)`.
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CENGAGE CHEMISTRY-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Multiple Correct)
  1. Which of the following statement(s) is/are correct?

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  2. In Q.No. 11, which of the following reagents can be used to convert (A...

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  3. Which of the following will give yellow precipitate with KOI?

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  4. Which of the following will undergo periodic oxidation?

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  5. Which of the following reactions is//are correct?

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  6. Which of the following reactions is//are correct?

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  7. Which statement(s) is/are wrong?

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  8. Which of the following reaction(s) is/are correct?

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  9. Which of the following reaction(s) is/are wrong?

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  10. Which of the following reactions is/are wrong?

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  11. Which of the following unbalanced reactions is/are correct?

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  12. Which of the following methods is/are correct for the synthesis of ben...

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  13. Which of the following reaction is/are correct?

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  14. Which of the following methods is/are correct for the synthesis of

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  15. Which of the following on oxidation with alkaline KMnO(4) follwed by a...

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  16. Which of the following methods can be used to prepare propanoic acid?

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  17. Which of the following statements is/are correct about formic acid?

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  18. Which of the following can reduce Benedict's solution?

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  19. Benzoic acid and carbolic acid can be distiguished by:

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  20. Which of the following compounds do(es) not give haloform reaction?

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