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Ketone (A), which indergoes halform reac...

Ketone `(A)`, which indergoes halform reaction, give compound `(B)` on reduction. `(B)` on heating with `H_(2)SO_(4)` gives compound `(C )`, which forms mono-ozonide `(D). (D)` on hydrolysis in the presence of `Zn` dust gives only acetaldehyde. Identify `(A). (B)`, and `(C )`. Write down the reactions involved.

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Ketone `(A)` gives haloform reaction, so it must contain `(Me-CO-)` group. Ketone on reduction gives `2^(@)` alcohol. (B), which gives alkene `(C )` with `H_(2)SO_(4)`. Alkene on ozonolysis followed by reduction with `Zn` dust gives `MeCHO`. So, the structure of alkene `(C )` is:

So `(A)` is: Butan-`2`-one, `(B)` is: Butan-`2`-ol, `(C )` is: Butan-`2`-one.
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CENGAGE CHEMISTRY-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise Archives (Subjective)
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  2. Which one of the following will most readily be dehydrated in acidic c...

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  3. 1-Propanol and 2- propanol can be distinguished by:

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  4. Compound (A) [molecular formula (C(3)H(8)O)] is treated with acidified...

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  5. PhC-=CPh overset(Hg^(2+)+H^(o+))to(A). The compound (A) is The comp...

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  6. The products of acid hydrolysis of P and Q can be distinguished by

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  7. How will you convert butan-2-one to propanoic acid?

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  8. Which of the following compound will give a yellow precipitate with io...

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  9. Under Wolff-Kishner reduction conditions, the conversion which may be ...

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  10. Fehling's solution 'A' consists of an aqueous solution of copper sulph...

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  11. The yield of ketone when a secondary alcohol is oxidised is more than ...

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  12. Statement I: Acetic acid does not undergo haloform reaction. Stateme...

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  13. Give a chemical test to distinguish between methanol and ethanol.

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  14. Suggest a suitable reagent to distinguish acetaldehyde from acetone.

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  15. Ketone (A), which indergoes halform reaction, give compound (B) on red...

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  16. Give reason on one or two sentances for the following: Iodoform is obt...

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  17. When t-butanol and n-butanol are separately treated with a few drops o...

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  18. A compound (D) (C(8)H(10)O) upon treatement with alkaline solution of ...

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  19. Identify (A), (B), and (C ) and give their strucyures.

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  20. An alkene (A) C(16)H(16) on ozonolysis gives only one product (B) (C(8...

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