Home
Class 12
CHEMISTRY
The standard emf for the cell cell react...

The standard emf for the cell cell reaction ` Zn + Cu^(2+) rarr Zn^(2+) + Cu ` is 1.10 volt at ` 25^@ C`. The emf for the cell reaction when ` 0.1 M Cu^(2+)` and ` 0.1 M ZN^(2+)` solutions are used at `25^@ =C` is .

A

1.10 V

B

0.110 V

C

`-1.10 V `

D

`-0.110`V

Text Solution

Verified by Experts

The correct Answer is:
A

`E_("cell") = E_("cell")^(@) + (0.0592)/(2) log _(10) ([Cu^(2+)])/([Zn^(2+)])`
As `[Cu^(2+)] = [Zn^(2+)] therefore E_(cell) = E_(cell)^(@) = 1.1 V `
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    NIKITA PUBLICATION|Exercise Questions From Competitive Exam|46 Videos
  • D-AND F-BLOCK ELEMENTS

    NIKITA PUBLICATION|Exercise MULTIPLE CHOICE QUESTIONS|515 Videos
  • GENERAL PRINCIPLES & PROCESSES OF ISOLATION OF ELEMENTS

    NIKITA PUBLICATION|Exercise Multiple choice questions|117 Videos

Similar Questions

Explore conceptually related problems

The standard emf of the cell Zn+Cu^(2+)rarrCu+Zn^(2+) is 1.10V at 25^(@)c the emf of the cell when 0.1 M Cu^(2)+ and 0.1 M Zn^(2+) solution are used will be

The measured e.m.f. at 25^(@)C for the cell reaction , Zn(S)+Cu^(2+)(1.0 M)to Cu(s) +Zn^(2+) (0.1 M) is 1.3 volt, Calculate E^(@) for the cell reaction.

The standard emf for the cell reaction, Zn+Cu^(2+) to Cu^(2+) to Cu+Zn^(2+)," is "1.1V" at "25^(@)C." If 0.1 M "Cu^(2+) and 0.1M Zn^(2+) solutions are used then

NIKITA PUBLICATION-ELECTROCHEMISTRY -Questions From Competitive Exam
  1. The standard emf for the cell cell reaction Zn + Cu^(2+) rarr Zn^(2+)...

    Text Solution

    |

  2. A current 0.5 ampere when passed through AgNO(3) solution for 193 sec....

    Text Solution

    |

  3. A factory produces 40 kg of calcium in two hours by electrolysis. How ...

    Text Solution

    |

  4. {:("Electrolyte",^^.^(oo)(Scm^(2)mol^(-1))),(KCl,149.9),(KNO(3),145.0)...

    Text Solution

    |

  5. At certain temperature and infinite dilution , the equivalent conducta...

    Text Solution

    |

  6. A solution of concentration 'C' g equiv/litre has a specific resistanc...

    Text Solution

    |

  7. The solution of CuSO(4) in which copper rod is immersed is diluted to ...

    Text Solution

    |

  8. The standard oxidation potential E^@ for the half cell reaction are ...

    Text Solution

    |

  9. The Gibbs energy for the decomposition of Al(2)O(3) at 500^(@)C is as ...

    Text Solution

    |

  10. The correct order of E(M^(2+)//M)^(@) Values with negative sign for th...

    Text Solution

    |

  11. The concentration of potassium ions inside a biological cell is at lea...

    Text Solution

    |

  12. The concentration of potassium ions inside a biological cell is at lea...

    Text Solution

    |

  13. For the reduction of silver ions with copper metal, the standard cell ...

    Text Solution

    |

  14. An increase in equivalent conductance of a strong electrolyte with dil...

    Text Solution

    |

  15. Which of the following expressions correctly repesents the equivalent ...

    Text Solution

    |

  16. Consider the following relations for emf of a electrochemical cell (...

    Text Solution

    |

  17. The equilibrium constant (K) for the reaction Cu(s)+2Ag^(+) (aq) rar...

    Text Solution

    |

  18. E^(@) for Fe//Fe^(2+) is +0.44 V and E^(@) for Cu//Cu^(2+) is -0.32 V....

    Text Solution

    |

  19. For the electrochemical cell, M|M^(+) ||X^(-)|X, E(M^(+)//M)^(@) = 0.4...

    Text Solution

    |

  20. Match the followings . {:(,"List - I" ,, ,"List- II") , (,(A) "Poten...

    Text Solution

    |

  21. If values of Lambda(0) of NH(4)Cl , NaOH and NaCl are 130 , 127 and 10...

    Text Solution

    |