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When 0.1 m "mole" of solid NaOH is added...

When `0.1 m "mole"` of solid `NaOH` is added in `1 L` of `0.1 M NH_(3) (aq)` then which statement is going to be wrong?
`(K_(b)=2xx10^(-5), log 2=0.3)`

A

degree of dissociation of `NH_(3)` approaches to zero.

B

change in `pH` would be `1.85`

C

concentration of `[Na^(+)]=0.1 M, [NH_(3)]=0.1 M`, `[OH^(-)]=0.2 M`

D

on addition of `OH^(-)`,`K_(b)` of `NH_(3)` does not changes

Text Solution

Verified by Experts

The correct Answer is:
C

Initial `pOH=(1)/(2)(pK_(b)-log C)`
`= (1)/(2)(4.7-log 0.1)=2.85`
Final `pOH=1`
Change in `pOH=`Change in `pH=1.85`
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A2Z-IONIC EQUILIBIUM-Salt Hydrolysis
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  6. Which is the correct alternate for hydrolysis constant of NH(4)CN?

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  8. Which of the following aqueous solution will have a pH less than 7.0 ?

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  9. Hydrolysis constant for a salt of weak acid and weak base would be

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  10. Which of salt will give basic solution on hydrolysis?

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  11. Which salt can be classified as an acid salt?

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  12. HA is a weak acid and BOH is a weak base. For which of the following s...

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  13. pH of water is 7. When a substance Y is dissolved in water, the pH bec...

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  14. Which is a basic salt

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  15. The pH of 0.02 M NH(4)Cl (aq) (pK(b)=4.73) is equal to

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  16. 100 ml of 0.1 M CH(3)COOH are mixed with 100ml of 0.1 M NaOH, the pH o...

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  17. A compound whose aqueous solution will have the highest pH

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