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In the reaction H(2)S+NO(2) rarr H(2)O...

In the reaction
`H_(2)S+NO_(2) rarr H_(2)O+NO+S.H_(2)S` is

A

Oxidised

B

Reduced

C

Precipitated

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine whether H₂S is oxidized, reduced, or undergoing another process in the reaction \( H_2S + NO_2 \rightarrow H_2O + NO + S + H_2S \), we need to analyze the changes in oxidation states of the elements involved. ### Step 1: Assign Oxidation Numbers 1. **For H₂S (Hydrogen Sulfide)**: - Hydrogen (H) has an oxidation state of +1. - Let the oxidation state of sulfur (S) be \( x \). - The overall charge of the molecule is 0, so: \[ 2(+1) + x = 0 \implies x = -2 \] - Therefore, the oxidation state of H₂S is: - H: +1 - S: -2 2. **For H₂O (Water)**: - Hydrogen (H) is +1. - Oxygen (O) is -2. - Thus, the oxidation states are: - H: +1 - O: -2 3. **For NO (Nitric Oxide)**: - Let the oxidation state of nitrogen (N) be \( y \). - Oxygen (O) is -2. - The overall charge of the molecule is 0, so: \[ y + (-2) = 0 \implies y = +2 \] - Therefore, the oxidation states are: - N: +2 - O: -2 4. **For S (Sulfur)**: - The elemental form of sulfur has an oxidation state of 0. ### Step 2: Analyze Changes in Oxidation Numbers - **In H₂S**: - Sulfur changes from -2 (in H₂S) to 0 (elemental S). - This is an increase in oxidation state, indicating oxidation. - **In NO₂**: - Nitrogen in NO₂ has an oxidation state of +4 (since O is -2). - In NO, nitrogen is +2. - This indicates a decrease in oxidation state, indicating reduction. ### Step 3: Conclusion Since sulfur in H₂S is oxidized (its oxidation state increases from -2 to 0), we conclude that: **H₂S is being oxidized in the reaction.** ### Final Answer H₂S is being oxidized. ---

To determine whether H₂S is oxidized, reduced, or undergoing another process in the reaction \( H_2S + NO_2 \rightarrow H_2O + NO + S + H_2S \), we need to analyze the changes in oxidation states of the elements involved. ### Step 1: Assign Oxidation Numbers 1. **For H₂S (Hydrogen Sulfide)**: - Hydrogen (H) has an oxidation state of +1. - Let the oxidation state of sulfur (S) be \( x \). - The overall charge of the molecule is 0, so: \[ ...
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Knowledge Check

  • In the reaction H_2S + NO_2 rarr H_2O + NO +S. H_2S is

    A
    oxidised
    B
    reduced
    C
    precipitated
    D
    None of these
  • In the reaction. H_(2)S+H_(2)O_(2) rarr S+2H_(2)O

    A
    `H_(2)S` is an and `H_(2)O_(2)` is a base
    B
    `H_(2)S` is a base and `H_(2)O_(2)` is an acid
    C
    `H_(2)S` is an oxidizing agent and `H_(2)O_(2)` is a reducing agent
    D
    `H_(2)S` is a reducing agent and `H_(2)O_(2)` is an oxidising agent
  • In the reaction, 2H_(2)S+SO_(2)to3S+2H_(2)O

    A
    `H_(2)S` has been oxidised
    B
    `SO_(2)` has been oxidised
    C
    `H_(2)S` is the oxidising agent
    D
    `SO_(2)` is the reducing agent.
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