Home
Class 11
CHEMISTRY
In the reaction H(2)S+NO(2) rarr H(2)O...

In the reaction
`H_(2)S+NO_(2) rarr H_(2)O+NO+S.H_(2)S` is

A

Oxidised

B

Reduced

C

Precipitated

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine whether H₂S is oxidized, reduced, or undergoing another process in the reaction \( H_2S + NO_2 \rightarrow H_2O + NO + S + H_2S \), we need to analyze the changes in oxidation states of the elements involved. ### Step 1: Assign Oxidation Numbers 1. **For H₂S (Hydrogen Sulfide)**: - Hydrogen (H) has an oxidation state of +1. - Let the oxidation state of sulfur (S) be \( x \). - The overall charge of the molecule is 0, so: \[ 2(+1) + x = 0 \implies x = -2 \] - Therefore, the oxidation state of H₂S is: - H: +1 - S: -2 2. **For H₂O (Water)**: - Hydrogen (H) is +1. - Oxygen (O) is -2. - Thus, the oxidation states are: - H: +1 - O: -2 3. **For NO (Nitric Oxide)**: - Let the oxidation state of nitrogen (N) be \( y \). - Oxygen (O) is -2. - The overall charge of the molecule is 0, so: \[ y + (-2) = 0 \implies y = +2 \] - Therefore, the oxidation states are: - N: +2 - O: -2 4. **For S (Sulfur)**: - The elemental form of sulfur has an oxidation state of 0. ### Step 2: Analyze Changes in Oxidation Numbers - **In H₂S**: - Sulfur changes from -2 (in H₂S) to 0 (elemental S). - This is an increase in oxidation state, indicating oxidation. - **In NO₂**: - Nitrogen in NO₂ has an oxidation state of +4 (since O is -2). - In NO, nitrogen is +2. - This indicates a decrease in oxidation state, indicating reduction. ### Step 3: Conclusion Since sulfur in H₂S is oxidized (its oxidation state increases from -2 to 0), we conclude that: **H₂S is being oxidized in the reaction.** ### Final Answer H₂S is being oxidized. ---

To determine whether H₂S is oxidized, reduced, or undergoing another process in the reaction \( H_2S + NO_2 \rightarrow H_2O + NO + S + H_2S \), we need to analyze the changes in oxidation states of the elements involved. ### Step 1: Assign Oxidation Numbers 1. **For H₂S (Hydrogen Sulfide)**: - Hydrogen (H) has an oxidation state of +1. - Let the oxidation state of sulfur (S) be \( x \). - The overall charge of the molecule is 0, so: \[ ...
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    A2Z|Exercise Balancing Of The Equation|28 Videos
  • REDOX REACTIONS

    A2Z|Exercise Stoichiometry In Redox Reactions|44 Videos
  • P BLOCK ELEMENTS ( Group 13 -14)

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • S BLOCK ELEMENTS ( GROUP 13 - 14)

    A2Z|Exercise Section D - Chapter End Test|29 Videos

Similar Questions

Explore conceptually related problems

In the reaction. H_(2)S+H_(2)O_(2) rarr S+2H_(2)O

In the equation H_(2)S+2HNO_(3) rarr 2H_(2)O+2NO_(2)+S The equivalent weight of hydrogen sulphide is

In the reaction H_(2)S+SO_(2) to S+H_(2)O, H_(2)S is

Equivalent mass of oxidizing agent in the reaction, SO_(2)+2H_(2)S rarr 3S+2H_(2)O is

In the reaction, H_(2)S+H_(2)SO_(4)toS+2H_(2)O

The reaction of H_(2)S+H_(2)O_(2) rarr S+2H_(2)O manifests

A2Z-REDOX REACTIONS-Section D - Chapter End Test
  1. In the reaction H(2)S+NO(2) rarr H(2)O+NO+S.H(2)S is

    Text Solution

    |

  2. For H(3)PO(3) and H(3)PO(4) the correct choice is

    Text Solution

    |

  3. The oxidation number of sulphur in H(2)S(2)O(7) and iron in K(4)Fe(CN)...

    Text Solution

    |

  4. One mole of N(2)H(4) loses ten moles of electrons to form a new compou...

    Text Solution

    |

  5. In the compound YBa(2)Cu(3)O(7) which shows superconductivity, what is...

    Text Solution

    |

  6. The oxidation number of S in S(8),S(2)F(2), and H(2)S, respectively, a...

    Text Solution

    |

  7. Which one of the following reactions is not an example of redox reacti...

    Text Solution

    |

  8. For the reaction, C+O(2)rarrCO(2), DeltaH=-393 J 2Zn+O(2) rarr 2ZnO,...

    Text Solution

    |

  9. In the reaction B(2)H(6)+2KOH+2Xrarr 2Y+6H(2), X and Y are respectivel...

    Text Solution

    |

  10. In a balanced equation H(2)SO(4)+xHI rarr H(2)S+YI(2)+zH(2)O, the valu...

    Text Solution

    |

  11. MnO(4)^(2-) (1 mole) in neutral aqueous medium is disproportionate to

    Text Solution

    |

  12. The conductivity of a saturated solution of BaSO4 is 3. 06 xx 10^(-6)...

    Text Solution

    |

  13. H(2)O(2) reduces K(4)Fe(CN)(6)

    Text Solution

    |

  14. When sodium metal is dissolved in liquid ammonia, blue colour solution...

    Text Solution

    |

  15. Which of the following is redox reaction ?

    Text Solution

    |

  16. In which of the following reactions H(2)O(2) is a reducing agent?

    Text Solution

    |

  17. Which is the best description of the behaviour of bromine in the react...

    Text Solution

    |

  18. Which of the following substances acts as an oxidising as well as a re...

    Text Solution

    |

  19. When K(2)Cr(2)O(7) is converted to K(2)CrO(4), the change in the oxida...

    Text Solution

    |

  20. Oxidation state of chlorine in perchloric acid is

    Text Solution

    |

  21. The oxidation number of S in H(2)S(2)O(8) is

    Text Solution

    |