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I^(-) reduces IO(3)^(-) and I(2) and its...

`I^(-)` reduces `IO_(3)^(-)` and `I_(2)` and itself oxidised to `I_(2)` in acidic medium. Thus, final reaction is

A

`I^(-)+IO_(3)^(-)+6H^(+) rarr I_(2)+3H_(2)O`

B

`5I^(-)+IO_(3)^(-)+6H^(+) rarr 3I_(2)+3H_(2)O`

C

`I^(-)+IO_(3)^(-) rarr I_(2)+O_(3)`

D

None of them

Text Solution

Verified by Experts

The correct Answer is:
B


To balance oxidation number, cross-multiply by change in oxidation number
`5I^(-)+IO_(3)^(-) rarr 3I_(2) rarr 3I_(2)+3H_(2)O` [balance (`O`) by `H_(2)O+6H^(+)`]
balance (`H`) by `H^(+)`
Thus, `5I^(-)+IO_(3)^(-)+6H^(+) rarr 3I_(2)+3H_(2)O`
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