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What is the equivalent weight of NH(3) i...

What is the equivalent weight of `NH_(3)` in the given reaction?
`3CuO+2NH_(3) rarr 3Cu+N_(2)+3H_(2)O`

A

`17`

B

`(17)/(4)`

C

`(17)/(2)`

D

`(17)/(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equivalent weight of \( NH_3 \) in the given reaction: \[ 3CuO + 2NH_3 \rightarrow 3Cu + N_2 + 3H_2O \] we will follow these steps: ### Step 1: Identify the change in oxidation states In the reaction, we need to determine how many electrons are transferred when \( NH_3 \) is oxidized to \( N_2 \). - In \( NH_3 \), nitrogen has an oxidation state of -3. - In \( N_2 \), nitrogen has an oxidation state of 0. ### Step 2: Calculate the change in oxidation state The change in oxidation state for one nitrogen atom is: \[ 0 - (-3) = 3 \] Since there are 2 nitrogen atoms in \( 2NH_3 \), the total change in oxidation state is: \[ 2 \times 3 = 6 \] ### Step 3: Determine the number of moles of \( NH_3 \) The balanced equation shows that 2 moles of \( NH_3 \) are used in the reaction. ### Step 4: Calculate the balance factor The balance factor is defined as the total number of electrons transferred divided by the number of moles of the substance involved. Therefore, for \( NH_3 \): \[ \text{Balance Factor} = \frac{\text{Total electrons transferred}}{\text{Number of moles of } NH_3} = \frac{6}{2} = 3 \] ### Step 5: Calculate the molecular weight of \( NH_3 \) The molecular weight of \( NH_3 \) is calculated as follows: - Nitrogen (N) = 14 g/mol - Hydrogen (H) = 1 g/mol (and there are 3 hydrogen atoms) Thus, the molecular weight of \( NH_3 \) is: \[ 14 + (3 \times 1) = 17 \text{ g/mol} \] ### Step 6: Calculate the equivalent weight The equivalent weight is given by the formula: \[ \text{Equivalent Weight} = \frac{\text{Molecular Weight}}{\text{Balance Factor}} = \frac{17}{3} \approx 5.67 \text{ g/equiv} \] ### Final Answer The equivalent weight of \( NH_3 \) in the given reaction is approximately \( 5.67 \text{ g/equiv} \). ---

To find the equivalent weight of \( NH_3 \) in the given reaction: \[ 3CuO + 2NH_3 \rightarrow 3Cu + N_2 + 3H_2O \] we will follow these steps: ...
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