Home
Class 11
CHEMISTRY
Wave number of spectral line for a given...

Wave number of spectral line for a given transition is `x cm^(-1)` for `He^(+)`, then its value for `Be^(3+)` (isoelectronic of `He^(+))` for same transition is:

A

(a)`x cm^(-1)`

B

(b)`4x cm^(-1)`

C

(c )`x/4 cm^(-1)`

D

(d)`2x cm^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

`bar(upsilon)` wave number `= bar(R)_(H)Z^(2)[1/n_(1)^(2)-1/n_(2)^(2)]`
`bar(upsilon) prop z^(2)` if `n_(1)` and `n_(2)` are same
`bar(upsilon)_(1)/bar(upsilon)_(2)=z_(2)^(1)/z_(2)^(2)implies x/bar(upsilon)_(2)=2^(2)/4^(2)`
`x/bar(upsilon)_(2)=4/(4xx4)implies upsilon_(2)=4x`
Promotional Banner

Topper's Solved these Questions

  • MOCK TEST

    A2Z|Exercise Mock Test 2|45 Videos
  • IONIC EQUILIBIUM

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • P BLOCK ELEMENTS ( Group 13 -14)

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

The ratio of the wavelengths for 2 rarr 1 transition in Li^(++), He^(+) and H is

Total number of spectral in UV region during transition from 5 ^(th) excited state to 1^(St) excited state

The wave number of a spectral line is 5xx10^(5)m^(-1) . The energy corresponding to this line is

Statement : Wave number of a spectral line for an electronic transition is quantised . Explanation : Wave number is directly proportional to the velocity of electron undergoing the transition .

What is the wavelength in nm of the spectral line associated with a transition from n=3 to n= 2 for the Li^(2+) ion?

The wave number of a spectral line is 5 xx 10^5 m^-1 . The energy corresponding to this line will be.

A : wavelength for first line of any series of hydrogen spectrum is biggest among all other lines of the same series . R : Wavelength of spectral line for an electron transition if inversely related to difference in the energy level involved in the transition .

A2Z-MOCK TEST-Mock Test 2
  1. Wave number of spectral line for a given transition is x cm^(-1) for H...

    Text Solution

    |

  2. Ethylene combines with sulphur monochloride to form.

    Text Solution

    |

  3. Benzene reacts with acetyl chloride in the prescence of anhydrous AlCl...

    Text Solution

    |

  4. R-C -= C - H overset (NaNH2)rarr A overset (RX)rarr B overset (Na//Liq...

    Text Solution

    |

  5. 20 ml of an H2 O2 solution on reaction with excess of acidified KMnO4 ...

    Text Solution

    |

  6. Hydrogen diffuses six times faster than gas A. The molar mass of gas A...

    Text Solution

    |

  7. Which of the following forms a homologous series ?

    Text Solution

    |

  8. Which of the following alkanes cannot be produced by Kolbe's electroly...

    Text Solution

    |

  9. Which is not a tetrahedral species ?

    Text Solution

    |

  10. A mixture of CO, CO2 and He on passing over red hot coke shows 40 % in...

    Text Solution

    |

  11. A gas with negligible intermolecular interactions shows compressibilit...

    Text Solution

    |

  12. Text Solution

    |

  13. The conductivity of a saturated solution of BaSO4 is 3. 06 xx 10^(-6)...

    Text Solution

    |

  14. The reaction proceeds through .

    Text Solution

    |

  15. IE "for" He^+ "is" 1.96 xx 10^-19 J "atom"^-1. Calculate the energy of...

    Text Solution

    |

  16. Which of the following compounds will exhibit d-orbital resonance ?

    Text Solution

    |

  17. The heat of atomisation of PH(3(g)) is 228kcal mol^(-1) and that of P(...

    Text Solution

    |

  18. Which of the following pairs of compounds may be regarded both as posi...

    Text Solution

    |

  19. The correct decreasing order of ionic size among the following species...

    Text Solution

    |

  20. One mole of symmetrical alkene on ozonolysis gives two moles of an ald...

    Text Solution

    |

  21. The Gibbs energy for the decomposition of FeO at 600^@ C is as follows...

    Text Solution

    |