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1 mol of H(3)PO(2), H(3)PO and H(3)PO(4)...

1 mol of `H_(3)PO_(2), H_(3)PO` and `H_(3)PO_(4)` will neutralise x mol `NaOH`, y mol of `Ca(OH)_(2)` and z mol of `Al(OH)_(2)` respectively (assuming all as strong electrolytes). x, y, z are in the ratio of:

A

(a)`3:1.5:1`

B

(b)`1:2:3`

C

(c )`3:2:1`

D

(d)`1:1:1`

Text Solution

Verified by Experts

The correct Answer is:
D

`H_(3)PO_(2) - "monobasic" -= 1 OH^(-) -= 1 NaOH`
`H_(3)PO_(3) - "dibasic" -= 2 OH -= 1 Ca(OH)_(2)`
`H_(3)PO_(4) - "tribasic" -= 3 OH^(-) = 1 Al(OH)_(3)`
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